Metal Ions Trigger the Gelation of Cysteine‐Containing Peptide‐Appended Coordination Cages
Abstract: We report a series of coordination cages that incorporate peptide chains at their vertices, prepared through subcomponent self‐assembly. Three distinct heterochiral tripeptide subcomponents were incorporated, each exhibiting an L−D−L stereoconfiguration. Through this approach, we prepared and characterized three tetrahedral metal‐peptide cages that incorporate thiol and methylthio groups. The gelation of these cages was probed through the binding of additional metal ions, with the metal‐peptide cages acting as junctions, owing to the presence of sulfur atoms on the peripheral peptides. Gels were obtained with cages bearing cysteine at the C‐terminus. Our strategy for developing functional metal‐coordinated supramolecular gels with a modular design may result in the development of materials useful for chemical separations or drug delivery.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Metal Ions Trigger the Gelation of Cysteine‐Containing Peptide‐Appended Coordination Cages ; day:14 ; month:06 ; year:2024 ; extent:7
Angewandte Chemie ; (14.06.2024) (gesamt 7)
- Creator
-
Li, Meng
Zhu, Huangtianzhi
Adorinni, Simone
Xue, Weichao
Heard, Andrew
Garcia, Ana M.
Kralj, Slavko
Nitschke, Jonathan
Marchesan, Silvia
- DOI
-
10.1002/ange.202406909
- URN
-
urn:nbn:de:101:1-2406141419471.847486610809
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
14.08.2025, 10:46 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Li, Meng
- Zhu, Huangtianzhi
- Adorinni, Simone
- Xue, Weichao
- Heard, Andrew
- Garcia, Ana M.
- Kralj, Slavko
- Nitschke, Jonathan
- Marchesan, Silvia
Other Objects (12)
Metal Ions Trigger the Gelation of Cysteine‐Containing Peptide‐Appended Coordination Cages
Calculating the most likely intron splicing orders in S. pombe, fruit fly, Arabidopsis thaliana, and humans
Temperature sensitivity of carbon concentrating mechanisms in the diatom Phaeodactylum tricornutum
Trends in GeTe Thermoelectrics: From Fundamentals to Applications
Risk factors of deep vein thrombosis of lower extremity in patients undergone gynecological laparoscopic surgery: what should we care
A vertical track nonlinear energy sink
Incorporating Real Option Value in Valuing Innovation: A Way Forward
Impaired neurogenesis and neural progenitor fate choice in a human stem cell model of SETBP1 disorder
Advances in Ionic Thermoelectrics: From Materials to Devices
Fluorescence Sensing with Cellulose‐Based Materials
Deep learning models for predicting the survival of patients with medulloblastoma based on a surveillance, epidemiology, and end results analysis
Strontium and Zinc Co-Doped Mesoporous Bioactive Glass Nanoparticles for Potential Use in Bone Tissue Engineering Applications
Metal Ions Trigger the Gelation of Cysteine‐Containing Peptide‐Appended Coordination Cages
Calculating the most likely intron splicing orders in S. pombe, fruit fly, Arabidopsis thaliana, and humans
Temperature sensitivity of carbon concentrating mechanisms in the diatom Phaeodactylum tricornutum
Trends in GeTe Thermoelectrics: From Fundamentals to Applications
Risk factors of deep vein thrombosis of lower extremity in patients undergone gynecological laparoscopic surgery: what should we care
A vertical track nonlinear energy sink
Incorporating Real Option Value in Valuing Innovation: A Way Forward
Impaired neurogenesis and neural progenitor fate choice in a human stem cell model of SETBP1 disorder
Advances in Ionic Thermoelectrics: From Materials to Devices
Fluorescence Sensing with Cellulose‐Based Materials
Deep learning models for predicting the survival of patients with medulloblastoma based on a surveillance, epidemiology, and end results analysis
Strontium and Zinc Co-Doped Mesoporous Bioactive Glass Nanoparticles for Potential Use in Bone Tissue Engineering Applications
Metal Ions Trigger the Gelation of Cysteine‐Containing Peptide‐Appended Coordination Cages
Calculating the most likely intron splicing orders in S. pombe, fruit fly, Arabidopsis thaliana, and humans
Temperature sensitivity of carbon concentrating mechanisms in the diatom Phaeodactylum tricornutum
Trends in GeTe Thermoelectrics: From Fundamentals to Applications
Risk factors of deep vein thrombosis of lower extremity in patients undergone gynecological laparoscopic surgery: what should we care
A vertical track nonlinear energy sink
Incorporating Real Option Value in Valuing Innovation: A Way Forward
Impaired neurogenesis and neural progenitor fate choice in a human stem cell model of SETBP1 disorder
Advances in Ionic Thermoelectrics: From Materials to Devices
Fluorescence Sensing with Cellulose‐Based Materials
Deep learning models for predicting the survival of patients with medulloblastoma based on a surveillance, epidemiology, and end results analysis