Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides
Abstract: The hydrogenolysis of glycerol was performed over a Pt/C catalyst in combination with several alkali metal hydroxides and their salts. LiOH was found to be an effective promoter for the selective hydrogenolysis of glycerol to 1,2-propanediol. Hydroxyl ions are the main factor to promote the reaction process by dehydration of the glyceraldehyde intermediate. Lithium ions play a role in assisting the dehydrogenation of glycerol to glyceraldehyde, because they have the right size to coordinate with the alkoxide species. A possible surface reaction mechanism involving the participation of lithium ions was proposed to account for the results obtained in the study.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides ; volume:14 ; number:1 ; year:2016 ; pages:279-286 ; extent:8
Open chemistry ; 14, Heft 1 (2016), 279-286 (gesamt 8)
- Creator
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Feng, Jian
Xiong, Wei
Ding, Hao
He, Bai
- DOI
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10.1515/chem-2016-0030
- URN
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urn:nbn:de:101:1-2410161548071.958266333258
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:28 AM CEST
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Associated
- Feng, Jian
- Xiong, Wei
- Ding, Hao
- He, Bai
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