Synthesis and electronic properties of pentacene derivatives as promising n-type semiconductor candidates
Abstract: Two pentacene derivatives 1 and 2 were synthesized from the Diels-Alder reactions of furan derivatives with 1,4-benzoquinone. They were characterized by the methods of 1H — nuclear magnetic resonance spectroscopy (1H-NMR), matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF MS), ultraviolet and visible spectrophotometry (UV-VIS), photoluminescence (PL) spectrometry and cyclic voltammetry (CV). The energy gaps of 1 and 2, taken directly from spectroscopic measurements, are broad as 2.72 and 2.46 eV, leading to blue and greenish blue photoluminescence, respectively. The LUMO and HOMO energy levels are −2.77 and −5.49 eV for 1, and −2.91 and −5.37 eV for 2, respectively. The low energy levels make both 1 and 2 good air-stabilities and promising n-type semiconductor candidates for use in organic electronics.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Synthesis and electronic properties of pentacene derivatives as promising n-type semiconductor candidates ; volume:4 ; number:4 ; year:2006 ; pages:723-731 ; extent:9
Open chemistry ; 4, Heft 4 (2006), 723-731 (gesamt 9)
- Creator
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Liu, Chengbin
Tang, Yanhong
Nie, Shuming
- DOI
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10.2478/s11532-006-0036-y
- URN
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urn:nbn:de:101:1-2410171644402.019560089315
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Associated
- Liu, Chengbin
- Tang, Yanhong
- Nie, Shuming
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