Stratospheric ozone depletion inside the volcanic plume shortly after the 2022 Hunga Tonga eruption

Abstract ∼ ∼ ∼ x and ClOx cycles and their interactions. Aside from the gas-phase chemistry, the heterogeneous reaction rate for HOCl + → 2  + 2 O increases to 104  cm- 3 - 1 + 2 is more important. The large water injection causes relative humidity over ice to increase to 70 %–100 %, decreases the H2 SO4  /2 O binary solution weight percent to 35 % compared with the 70 % ambient value, and decreases the plume temperature by 2–6 K. These changes lead to high heterogeneous reaction rates. Plume lofting of ozone-poor air is evident during the first 2 d after the eruption, but ozone concentrations quickly recover because its chemical lifetime is short at 20 hPa. With such a large seawater injection, we expect that ∼ ∼ x changes are probably not the reason for the HTHH initial in-plume O3 loss.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Stratospheric ozone depletion inside the volcanic plume shortly after the 2022 Hunga Tonga eruption ; volume:23 ; number:20 ; year:2023 ; pages:13355-13367 ; extent:13
Atmospheric chemistry and physics ; 23, Heft 20 (2023), 13355-13367 (gesamt 13)

Urheber
Zhu, Yunqian
Portmann, Robert W.
Kinnison, Douglas
Toon, Owen Brian
Millán, Luis
Zhang, Jun
Vömel, Holger
Tilmes, Simone
Bardeen, Charles G.
Wang, Xinyue
Evan, Stephanie
Randel, William J.
Rosenlof, Karen H.

DOI
10.5194/acp-23-13355-2023
URN
urn:nbn:de:101:1-2023102604281490640726
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
14.08.2025, 10:55 MESZ

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Beteiligte

  • Zhu, Yunqian
  • Portmann, Robert W.
  • Kinnison, Douglas
  • Toon, Owen Brian
  • Millán, Luis
  • Zhang, Jun
  • Vömel, Holger
  • Tilmes, Simone
  • Bardeen, Charles G.
  • Wang, Xinyue
  • Evan, Stephanie
  • Randel, William J.
  • Rosenlof, Karen H.

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