Isolation and characterization of the homoleptic nii and niii bis‐benzene sandwich cations

to connected objects

Abstract: A stable salt of the metalloradical [Ni(C6H6)2]+ hitherto unknown in the condensed phase was synthesized from [Ni(CO)4]+[WCA]– and benzene ([WCA]– = [F{Al(ORF)3}2]–; RF = C(CF3)3). Single crystal XRD reveals a remarkable asymmetrically η3, η6-slipped sandwich structure. The magnetic properties of the [Ni(C6H6)2]+ cation were determined in solution and in the gas phase. Oxidation with the synergistic Ag+/0.5 l2 system led to the salt [Ni(C6H6)2]2+ ([WCA]–)2 and all products were fully characterized by means of IR, Raman, NMR/EPR, single crystal and powder XRD

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Notes: Angewandte Chemie. International edition. - 61, 50 (2022) , e202211555, ISSN: 1521-3773

Event: Veröffentlichung

(where): Freiburg

(who): Universität

(when): 2022

Creator: Schmitt, Manuel
Mayländer, Maximilian
Heizmann, Tim
Richert, Sabine
Bülow, Christine
Hirsch, Konstantin
Zamudio-Bayer, Vicente
Lau, J. Tobias
Krossing, Ingo

Contributor: Magnetische Resonanz

DOI: 10.1002/anie.202211555

URN: urn:nbn:de:bsz:25-freidok-2305675

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 25.03.2025, 1:46 PM CET

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.

Show original at data provider

Associated

Time of origin

2022

Other Objects (12)

[Ni(CO)4]+ as NiI synthon: synthesis and characterization of NiI half‐sandwich and sandwich cations

From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

Hochschulschrift

Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett

Hochschulschrift

Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide

Stable salts of heteroleptic iron carbonyl/nitrosyl cations

Hochschulschrift

Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides

Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

Hochschulschrift

The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions

Hochschulschrift

Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen

Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations

Synthesis and structural characterization of Gallium(I) and Indium(I) cations coordinated by pentamethylethylenediamine

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

[Ni(CO)4]+ as NiI synthon: synthesis and characterization of NiI half‐sandwich and sandwich cations

From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

Hochschulschrift

Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett

Hochschulschrift

Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide

Stable salts of heteroleptic iron carbonyl/nitrosyl cations

Hochschulschrift

Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides

Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

Hochschulschrift

The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions

Hochschulschrift

Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen

Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations

Synthesis and structural characterization of Gallium(I) and Indium(I) cations coordinated by pentamethylethylenediamine

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

[Ni(CO)4]+ as NiI synthon: synthesis and characterization of NiI half‐sandwich and sandwich cations

From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

Hochschulschrift

Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett

Hochschulschrift

Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide

Stable salts of heteroleptic iron carbonyl/nitrosyl cations

Hochschulschrift

Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides

Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

Hochschulschrift

The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions

Hochschulschrift

Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen

Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations

Synthesis and structural characterization of Gallium(I) and Indium(I) cations coordinated by pentamethylethylenediamine

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

Cultural heritage institutions wishing to register will find more information here.

Fields marked * need to be filled in.

Username*

Please enter your username

Email*

Please enter your email address

Please do not fill this field

First name

Last name

Password*

Please enter your password

Confirm password*

Please enter the same password

I have read the terms of use and the privacy policy for the collection of personal data and accept them. *

This field is required.

I would like to subscribe to the newsletter of the Deutsche Digitale Bibliothek. See newsletter subscription info.

Account created

Your "My DDB" account has been successfully created. Before you can log in to your account, you must click the confirmation link in the message we just sent to the email address you provided.

Isolation and characterization of the homoleptic nii and niii bis‐benzene sandwich cations

Object Details

Contributors, Places and Time

Further information

Data provider

Associated

Time of origin

Other Objects (12)

[Ni(CO)4]+ as NiI synthon: synthesis and characterization of NiI half‐sandwich and sandwich cations

From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide

Stable salts of heteroleptic iron carbonyl/nitrosyl cations

Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides

Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions

Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen

Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations

Synthesis and structural characterization of Gallium(I) and Indium(I) cations coordinated by pentamethylethylenediamine

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

[Ni(CO)4]+ as NiI synthon: synthesis and characterization of NiI half‐sandwich and sandwich cations

From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide

Stable salts of heteroleptic iron carbonyl/nitrosyl cations

Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides

Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions

Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen

Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations

Synthesis and structural characterization of Gallium(I) and Indium(I) cations coordinated by pentamethylethylenediamine

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

[Ni(CO)4]+ as NiI synthon: synthesis and characterization of NiI half‐sandwich and sandwich cations

From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide

Stable salts of heteroleptic iron carbonyl/nitrosyl cations

Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides

Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions

Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen

Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations

Synthesis and structural characterization of Gallium(I) and Indium(I) cations coordinated by pentamethylethylenediamine

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

Related objects

Reset password