The inverted philosopher’s stone: how to turn silver to a base metal

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Abstract: Metals often are classified as “noble” or “base”—characterizing their reduction potential as one of the most important chemical properties. We show that metals are only as noble as allowed by their environment, i.e. this is a relative term, and the “frame of reference” simply is the solvent in which the redox system is present. We prove that silver is a prime example for a noble metal that forfeits its noble character in the simple ionic liquid HMIM Br (1-hexyl-3-methylimidazolium bromide) as an example for such a solvent

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Notes: Journal of solid state electrochemistry. - 24, 11-12 (2020) , 2847-2852, ISSN: 1433-0768

Keyword: Wasserstoffelektrode
Ionische Flüssigkeit
Ionensolvatation

Event: Veröffentlichung

(where): Freiburg

(who): Universität

(when): 2020

Creator: Radtke, Valentin
Pütz, Katharina
Himmel, Daniel
Krossing, Ingo

DOI: 10.1007/s10008-020-04633-y

URN: urn:nbn:de:bsz:25-freidok-1680143

Rights: Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 25.03.2025, 1:48 PM CET

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2020

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The inverted philosopher’s stone: how to turn silver to a base metal

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Other Objects (12)

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Stack by stack: from the free cyclopentadienylgermanium cation via heterobimetallic main‐group sandwiches to main‐group sandwich coordination polymers

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From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations

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The contribution of molecular interaction potentials to properties and activities of ionic liquid ions in solution

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The contribution of molecular interaction potentials to properties and activities of ionic liquid ions in solution

From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster

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