Catalytic Main‐group Metal Complexes of Phosphine‐based Pincer Ligands
Abstract: Pincer ligand complexes, which appeared nearly five decades ago, have provided a valuable platform for the study of fundamental chemical processes and the development of efficient catalysts for many chemical transformations. These complexes have usually contained transition metal atoms or ions, and their respective pincer ligands have often featured phosphine donor groups, which strongly coordinate to the metal center and allow its steric and electronic properties to be fine‐tuned. The increasing need to develop cost‐effective and sustainable catalytic processes has driven the search for main‐group metals as alternatives to commonly‐used transition metals. In this review, we show that despite the inherent mismatch between phosphines, which are soft Lewis bases, and main‐group metal ions, which are hard Lewis acids, a series of well‐defined phosphine‐based pincer complexes containing Li (I), Na (I), K (I), Mg (II), Ca (II), Zn (II) and Al (III) have been reported, which have proven to be active catalysts for industrially‐relevant transformations.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Catalytic Main‐group Metal Complexes of Phosphine‐based Pincer Ligands ; day:28 ; month:07 ; year:2023 ; extent:30
Israel journal of chemistry ; (28.07.2023) (gesamt 30)
- Creator
-
Montag, Michael
Milstein, David
- DOI
-
10.1002/ijch.202300082
- URN
-
urn:nbn:de:101:1-2023072915134144939475
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
14.08.2025, 10:48 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Montag, Michael
- Milstein, David
Other Objects (12)
Alternatives to phosphorus‐containing pincer ligands in catalytic hydrogenation
Molybdenum pincer complexes : synthesis and application in catalytic hydrogenations
Complexes of rhenium and technetium with multidentate phosphine ligands
Biological and Catalytic Applications of Pd (II)‐Indenyl Complexes Bearing Phosphine and N ‐Heterocyclic Carbene Ligands
Rhodium (I) PNN Pincer Complexes with Proton‐responsive Ligands: Synthesis, Characterisation, and Catalytic Dehydrocoupling of Amine Boranes
Biphenyl-Based Phosphine Ligands
Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P,O] ligands
N-Heterocyclic Carbene Palladium Pincer Complexes: Synthesis, Aggregations and Catalytic Applications
Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN3P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism
Influence of η 1 ‐Acetylide Ligands on the Spin State and Catalytic Activity of Iron (II) PNP Pincer Complexes
Chiral amino-phosphine and amido-phosphine complexes of Ir and Mg. Catalytic applications in olefin hydroamination
Two-in-one Pincer Type Ligands and Their Metal Complexes for Catalysis
Alternatives to phosphorus‐containing pincer ligands in catalytic hydrogenation
Molybdenum pincer complexes : synthesis and application in catalytic hydrogenations
Complexes of rhenium and technetium with multidentate phosphine ligands
Biological and Catalytic Applications of Pd (II)‐Indenyl Complexes Bearing Phosphine and N ‐Heterocyclic Carbene Ligands
Rhodium (I) PNN Pincer Complexes with Proton‐responsive Ligands: Synthesis, Characterisation, and Catalytic Dehydrocoupling of Amine Boranes
Biphenyl-Based Phosphine Ligands
Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P,O] ligands
N-Heterocyclic Carbene Palladium Pincer Complexes: Synthesis, Aggregations and Catalytic Applications
Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN3P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism
Influence of η 1 ‐Acetylide Ligands on the Spin State and Catalytic Activity of Iron (II) PNP Pincer Complexes
Chiral amino-phosphine and amido-phosphine complexes of Ir and Mg. Catalytic applications in olefin hydroamination
Two-in-one Pincer Type Ligands and Their Metal Complexes for Catalysis
Alternatives to phosphorus‐containing pincer ligands in catalytic hydrogenation
Molybdenum pincer complexes : synthesis and application in catalytic hydrogenations
Complexes of rhenium and technetium with multidentate phosphine ligands
Biological and Catalytic Applications of Pd (II)‐Indenyl Complexes Bearing Phosphine and N ‐Heterocyclic Carbene Ligands
Rhodium (I) PNN Pincer Complexes with Proton‐responsive Ligands: Synthesis, Characterisation, and Catalytic Dehydrocoupling of Amine Boranes
Biphenyl-Based Phosphine Ligands
Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P,O] ligands
N-Heterocyclic Carbene Palladium Pincer Complexes: Synthesis, Aggregations and Catalytic Applications
Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN3P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism
Influence of η 1 ‐Acetylide Ligands on the Spin State and Catalytic Activity of Iron (II) PNP Pincer Complexes
Chiral amino-phosphine and amido-phosphine complexes of Ir and Mg. Catalytic applications in olefin hydroamination