Binding Interactions in Copper, Silver and Gold π‐Complexes
Abstract: The copper (I), silver (I), and gold (I) metals bind π‐ligands by σ‐bonding and π‐back bonding interactions. These interactions were investigated using bidentate ancillary ligands with electron donating and withdrawing substituents. The π‐ligands span from ethylene to larger terminal and internal alkenes and alkynes. Results of X‐ray crystallography, NMR, and IR spectroscopy and gas phase experiments show that the binding energies increase in the order Ag
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Binding Interactions in Copper, Silver and Gold π‐Complexes ; day:08 ; month:02 ; year:2022 ; extent:1
Chemistry - a European journal ; (08.02.2022) (gesamt 1)
- Urheber
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Mehara, Jaya
Watson, Brandon T.
Noonikara‐Poyil, Anurag
Zacharias, Adway O.
Roithova, Jana
Dias, H. V. Rasika
- DOI
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10.1002/chem.202103984
- URN
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urn:nbn:de:101:1-2022020814163423229207
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:25 MESZ
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Beteiligte
- Mehara, Jaya
- Watson, Brandon T.
- Noonikara‐Poyil, Anurag
- Zacharias, Adway O.
- Roithova, Jana
- Dias, H. V. Rasika
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