Molecular-scale description of interfacial mass transfer in phase-separated aqueous secondary organic aerosol
Abstract k o/w = 0.03) and a concentration gradient of water in the organic shell at the higher temperature, while entropic effects are negligible at 200 K due to the association-entropic-term reduction in the free-energy profiles. The concentration gradient, which results from non-ideal mixing – and is a major factor in increasing LLPS CCN activity – is responsible for maintaining liquid–liquid phase separation and low surface tension even at very high relative humidities, thus reducing critical supersaturations. Thermodynamic driving forces are rationalized to be generalizable across different compositions. The conditions under which single uptake coefficients can be used to describe growth kinetics as a function of temperature in LLPS particles are described.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Molecular-scale description of interfacial mass transfer in phase-separated aqueous secondary organic aerosol ; volume:21 ; number:23 ; year:2021 ; pages:17687-17714 ; extent:28
Atmospheric chemistry and physics ; 21, Heft 23 (2021), 17687-17714 (gesamt 28)
- Urheber
- DOI
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10.5194/acp-21-17687-2021
- URN
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urn:nbn:de:101:1-2021120904262494419154
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:22 MESZ
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Beteiligte
- Lbadaoui-Darvas, Mária
- Takahama, Satoshi
- Nenes, Athanasios
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