Photo‐Induced Radicals in Carbon Nitride and their Magnetic Signature

Abstract: As a metal‐free semiconductor, carbon nitride is a promising material for sustainable photocatalysis. From the large number of studies, it seems apparent that the photocatalytic activity is related to the number and type of defects present in the structure. Many defects are paramagnetic and photoresponsive and, for these reasons, Electron Paramagnetic Resonance (EPR) spectroscopy is a powerful method to derive fundamental information on the structure – local, extended and electronic – of such defects which in turn impact the optical, magnetic and chemical properties of a material. This review aims at critically discussing the interpretation of EPR data of native and photoinduced radical defects in carbon nitride research highlighting strengths and limitations of this spectroscopic technique.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Photo‐Induced Radicals in Carbon Nitride and their Magnetic Signature ; day:13 ; month:02 ; year:2024 ; extent:13
ChemPhotoChem ; (13.02.2024) (gesamt 13)

Creator
Actis, Arianna
Fornasiero, Paolo
Chiesa, Mario
Salvadori, Enrico

DOI
10.1002/cptc.202300203
URN
urn:nbn:de:101:1-2024021314391005404049
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:31 AM CEST

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Associated

  • Actis, Arianna
  • Fornasiero, Paolo
  • Chiesa, Mario
  • Salvadori, Enrico

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