Minimizing Side Product Formation in Alkyne Functionalization of Ruthenium Complexes by Introduction of Protecting Groups
The synthesis of alkyne functionalized bipyridine ruthenium complexes are reported. The improved synthetic approach through application of stable protecting groups prevents formation of possible side products while facilitating purification. By applying copper‐catalysed azide‐alkyne cycloaddition reactions (CuAAC) pyrene units with flexible alkyl linkers are introduced at the periphery of the complex, opening up various applications including surface immobilization and DNA intercalation. All complexes are characterized structurally as well as photophysically, especially regarding the influence of the introduced alkyne and triazolyl substituents on their photophysical behavior.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Minimizing Side Product Formation in Alkyne Functionalization of Ruthenium Complexes by Introduction of Protecting Groups ; volume:646 ; number:13 ; year:2020 ; pages:842-848 ; extent:7
Zeitschrift für anorganische und allgemeine Chemie ; 646, Heft 13 (2020), 842-848 (gesamt 7)
- Creator
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Wintergerst, Pascal
Witas, Kamil
Nauroozi, Djawed
Schmid, Marie‐Ann
Dikmen, Ebru
Tschierlei, Stefanie
Rau, Sven
- DOI
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10.1002/zaac.202000042
- URN
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urn:nbn:de:101:1-2022062307050099009861
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Associated
- Wintergerst, Pascal
- Witas, Kamil
- Nauroozi, Djawed
- Schmid, Marie‐Ann
- Dikmen, Ebru
- Tschierlei, Stefanie
- Rau, Sven
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Direct Functionalization of Lithium Phosphine Oxides Bearing an Alkyne Chain
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