Access to 2,2‐Halofluorobicyclo (1.1.1) Pentanes via Non Ozone‐Depleting Ethyl Dihalofluoroacetate

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Abstract: An operationally simple protocol to access 2,2‐chlorofluoro‐, and 2,2‐bromofluorobicyclopentanes (BCPs) via commercially available, inexpensive, non‐ozone depleting, and bench stable reagents is reported. The resulting BCP products are tolerated in diverse, synthetically relevant post‐functionalization reactions. Gram‐scale reactions to prepare the BCPs are also included.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Access to 2,2‐Halofluorobicyclo (1.1.1) Pentanes via Non Ozone‐Depleting Ethyl Dihalofluoroacetate ; day:04 ; month:03 ; year:2025 ; extent:6
Advanced synthesis & catalysis ; (04.03.2025) (gesamt 6)

Urheber
Zhu, Ziyue
Tang, Jiaqi
Coe, Matthew
Knieb, Alexander
Xu, Yijie
Lin, Daniel
Zhang, Chao
Surya Prakash, G. K.

DOI
10.1002/adsc.202401475
URN
urn:nbn:de:101:1-2503051308536.104431918555
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:35 MESZ

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Beteiligte

  • Zhu, Ziyue
  • Tang, Jiaqi
  • Coe, Matthew
  • Knieb, Alexander
  • Xu, Yijie
  • Lin, Daniel
  • Zhang, Chao
  • Surya Prakash, G. K.

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