Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals
Abstract: Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid‐state as well as vapor‐phase reactions. By means of a combination of in situ X‐ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals ; volume:56 ; number:48 ; year:2017 ; pages:15267-15273 ; extent:7
Angewandte Chemie / International edition. International edition ; 56, Heft 48 (2017), 15267-15273 (gesamt 7)
- Creator
-
Abellán, Gonzalo
Neiss, Christian
Lloret, Vicent
Wild, Stefan
Chacón‐Torres, Julio C.
Werbach, Katharina
Fedi, Filippo
Shiozawa, Hidetsugu
Görling, Andreas
Peterlik, Herwig
Pichler, Thomas
Hauke, Frank
Hirsch, Andreas
- DOI
-
10.1002/anie.201707462
- URN
-
urn:nbn:de:101:1-2022091405585500571369
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:25 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Abellán, Gonzalo
- Neiss, Christian
- Lloret, Vicent
- Wild, Stefan
- Chacón‐Torres, Julio C.
- Werbach, Katharina
- Fedi, Filippo
- Shiozawa, Hidetsugu
- Görling, Andreas
- Peterlik, Herwig
- Pichler, Thomas
- Hauke, Frank
- Hirsch, Andreas
Other Objects (12)