Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals

Abstract: Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid‐state as well as vapor‐phase reactions. By means of a combination of in situ X‐ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals ; volume:56 ; number:48 ; year:2017 ; pages:15267-15273 ; extent:7
Angewandte Chemie / International edition. International edition ; 56, Heft 48 (2017), 15267-15273 (gesamt 7)

Creator
Abellán, Gonzalo
Neiss, Christian
Lloret, Vicent
Wild, Stefan
Chacón‐Torres, Julio C.
Werbach, Katharina
Fedi, Filippo
Shiozawa, Hidetsugu
Görling, Andreas
Peterlik, Herwig
Pichler, Thomas
Hauke, Frank
Hirsch, Andreas

DOI
10.1002/anie.201707462
URN
urn:nbn:de:101:1-2022091405585500571369
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:25 AM CEST

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