Investigations of ternary complexes of Co (II) and Ni (II) with thiodiacetate anion and 1,10-phenanthroline or 2,2’-bipyridine in aqueous solutions
Abstract: A potentiometric titration method (PT) and a stopped-flow kinetic technique monitored by a UV−Vis spectroscopy have been used to characterize the stability of series of Co (II)- and Ni (II)-thiodiacetato complexes, M (TDA), in the presence of 1,10-phenanthroline (phen) or 2,2’-bipyridine (bipy) in aqueous solutions. The stability constants of the binary (1:1), ternary (1:1:1) as well as the resulting hydroxo complexes were evaluated and compared to the corresponding oxydiacetate complexes. Based on the species distribution as a function of pH the relative predominance of the species in the system over a pH range was discussed. Furthermore, the kinetic measurements of the substitution reactions of the aqua ligands to phen or bipy in the coordination sphere of the binary complexes M (TDA) were performed in the 288–303 K temperature range, at a constant concentration of phen or bipy and at seven different concentrations of the binary complexes (0.2–0.5 mM). The kinetic stability of the M (TDA) complexes was discussed in relation to the experimental conditions and the kind of the auxiliary ligands (phen/bipy). Moreover, the influence of the type of primary ligand (thiodiacetate/oxydiacetate) on the substitution rate of the auxiliary ligands was also compared.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Investigations of ternary complexes of Co (II) and Ni (II) with thiodiacetate anion and 1,10-phenanthroline or 2,2’-bipyridine in aqueous solutions ; volume:13 ; number:1 ; year:2014 ; extent:7
Open chemistry ; 13, Heft 1 (2014) (gesamt 7)
- Creator
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Wyrzykowski, Dariusz
Pranczk, Joanna
Jacewicz, Dagmara
Tesmar, Aleksandra
Pilarski, Bogusław
Chmurzyński, Lech
- DOI
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10.1515/chem-2015-0048
- URN
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urn:nbn:de:101:1-2410151804224.663519855021
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:27 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Wyrzykowski, Dariusz
- Pranczk, Joanna
- Jacewicz, Dagmara
- Tesmar, Aleksandra
- Pilarski, Bogusław
- Chmurzyński, Lech
Other Objects (12)
Investigations of ternary complexes of Co (II) and Ni (II) with oxydiacetate anion and 1,10-phenanthroline or 2,2′-bipyridine in solutions
Organic four‐electron redox systems based on bipyridine and phenanthroline carbene architectures
Organic Four‐Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene Architectures
Synthesis of bipyridine-N-oxides and bipyridine-N,N'-dioxides
Konkave 1,10-Phenanthroline
Phenanthroline-Porphyrin Hybrid as a Fluorescence Sensor for Magnesium(II)
Effects of the tetravanadate [V4O12]4− anion on the structural, magnetic, and biological properties of copper/phenanthroline complexes
CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands
Cytotoxic Activities of Bis‐cyclometalated M (III) Complexes (M =Rh, Ir) Containing 5‐substituted 1,10‐Phenanthroline or 4,4’‐substituted 2,2’‐Bipyridine Ligands
New Challenge for Classics : Neutral Zinc Complexes Stabilised by 2,2’-Bipyridine and 1,10-Phenanthroline and Their Application in the Ring-Opening Polymerisation of Lactide
Ruthenacarborane–Phenanthroline Derivatives as Potential Metallodrugs
Untersuchungen über die Elektronenanregung der Phenanthroline
Investigations of ternary complexes of Co (II) and Ni (II) with oxydiacetate anion and 1,10-phenanthroline or 2,2′-bipyridine in solutions
Organic four‐electron redox systems based on bipyridine and phenanthroline carbene architectures
Organic Four‐Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene Architectures
Synthesis of bipyridine-N-oxides and bipyridine-N,N'-dioxides
Konkave 1,10-Phenanthroline
Phenanthroline-Porphyrin Hybrid as a Fluorescence Sensor for Magnesium(II)
Effects of the tetravanadate [V4O12]4− anion on the structural, magnetic, and biological properties of copper/phenanthroline complexes
CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands
Cytotoxic Activities of Bis‐cyclometalated M (III) Complexes (M =Rh, Ir) Containing 5‐substituted 1,10‐Phenanthroline or 4,4’‐substituted 2,2’‐Bipyridine Ligands
New Challenge for Classics : Neutral Zinc Complexes Stabilised by 2,2’-Bipyridine and 1,10-Phenanthroline and Their Application in the Ring-Opening Polymerisation of Lactide
Ruthenacarborane–Phenanthroline Derivatives as Potential Metallodrugs
Untersuchungen über die Elektronenanregung der Phenanthroline
Investigations of ternary complexes of Co (II) and Ni (II) with oxydiacetate anion and 1,10-phenanthroline or 2,2′-bipyridine in solutions
Organic four‐electron redox systems based on bipyridine and phenanthroline carbene architectures
Organic Four‐Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene Architectures
Synthesis of bipyridine-N-oxides and bipyridine-N,N'-dioxides
Konkave 1,10-Phenanthroline
Phenanthroline-Porphyrin Hybrid as a Fluorescence Sensor for Magnesium(II)
Effects of the tetravanadate [V4O12]4− anion on the structural, magnetic, and biological properties of copper/phenanthroline complexes
CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands
Cytotoxic Activities of Bis‐cyclometalated M (III) Complexes (M =Rh, Ir) Containing 5‐substituted 1,10‐Phenanthroline or 4,4’‐substituted 2,2’‐Bipyridine Ligands
New Challenge for Classics : Neutral Zinc Complexes Stabilised by 2,2’-Bipyridine and 1,10-Phenanthroline and Their Application in the Ring-Opening Polymerisation of Lactide
Ruthenacarborane–Phenanthroline Derivatives as Potential Metallodrugs