Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols
We report a Brønsted acid catalyzed enantioselective silylation of biaryl diols with an allylsilane as a silicon source. This process enables facile access to enantioenriched biaryl silyl ethers with an axial stereogenicity. A control experiment supports a mechanism proceeding by desymmetrization followed by kinetic resolution.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols ; day:12 ; month:07 ; year:2023
Synlett ; (12.07.2023)
- Contributor
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Han, Jung Tae
Zhou, Hui
List, Benjamin
- DOI
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10.1055/a-2100-1575
- URN
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urn:nbn:de:101:1-2023083110213095785549
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:54 AM CEST
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Associated
- Han, Jung Tae
- Zhou, Hui
- List, Benjamin
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