Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

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Abstract: The paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe (H2O) 4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysis. Magnetic properties, due to the presence of paramagnetic iron (II) centers, are presented and discussed.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers ; volume:2 ; number:2 ; year:2004 ; pages:323-333 ; extent:11
Open chemistry ; 2, Heft 2 (2004), 323-333 (gesamt 11)

Creator: Patrut, Adrian
Nicoara, Adrian
Margineanu, Dragos
Koop, Michael
Kögerler, Paul
Bögge, Hartmut
Schmidtmann, Marc

DOI: 10.2478/BF02475576

URN: urn:nbn:de:101:1-2410171651474.166900436380

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:20 AM CEST

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Associated

Patrut, Adrian
Nicoara, Adrian
Margineanu, Dragos
Koop, Michael
Kögerler, Paul
Bögge, Hartmut
Schmidtmann, Marc

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