A Trithia‐Bridged N ‐Heterotriangulene: The Hitherto Missing Electron Donor
Abstract: The very first representative of trithia‐bridged N‐heterotriangulene, a triphenylamine with sulfur atoms bridging the ortho‐positions, was synthesized by a sequence of regioselective sulfenylation with phthalimidesulfenyl chloride followed by Lewis acid‐catalyzed electrophilic cyclization. X‐ray crystallography revealed a saddle‐shaped geometry of the polycyclic scaffold. UV/Vis absorption spectroscopy and cyclic voltammetry were used to characterize the optoelectronic properties. The title compound is a particularly strong electron donor forming a perfectly stable radical cation, which was analyzed by electron paramagnetic resonance spectroscopy and X‐ray crystallography. The electron donor properties were further highlighted by the formation of crystalline donor‐acceptor complexes with strong cyano‐based acceptors.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
A Trithia‐Bridged N ‐Heterotriangulene: The Hitherto Missing Electron Donor ; day:27 ; month:12 ; year:2024 ; extent:8
Angewandte Chemie / International edition. International edition ; (27.12.2024) (gesamt 8)
- Urheber
-
Borstelmann, Jan
Gensch, Viktoria
Fehn, Dominik
Miehlich, Matthias E.
Hampel, Frank
Rominger, Frank
Meyer, Karsten
Kivala, Milan
- DOI
-
10.1002/anie.202423802
- URN
-
urn:nbn:de:101:1-2412271319505.046420121085
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:35 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Borstelmann, Jan
- Gensch, Viktoria
- Fehn, Dominik
- Miehlich, Matthias E.
- Hampel, Frank
- Rominger, Frank
- Meyer, Karsten
- Kivala, Milan
Ähnliche Objekte (12)
A Trithia‐Bridged N ‐Heterotriangulene: The Hitherto Missing Electron Donor
Donor‐Stabilized Monocarba‐Bridged Bis (cyclopentadienyl) alanes
(Spectro-)electrochemical characterisation of bridged donor-acceptor compounds
Macrocyclic Oligothiophene Bridged Perylene Bisimide Donor−Acceptor Dyads
Chapter III: Old Age; extant pictures hitherto unmentioned; missing and doubtful paintings
Electron delocalization in mixed-valence butadienediyl-bridged diruthenium complexes
On the mechanism of photoinduced electron transfer in bridged donor-acceptor systems : ferrocenophane-nileblue and rhodamine6G endcapping the DNA duplex
Fluorine donor bound electron spins as qubits
Fluorine donor bound electron spins as quibits
Nitrite, an Electron Donor for Anoxygenic Photosynthesis
Electrochemical redox properties of bridged and non‐bridged annulenediones
A hitherto unknown Meissonier
A Trithia‐Bridged N ‐Heterotriangulene: The Hitherto Missing Electron Donor
Donor‐Stabilized Monocarba‐Bridged Bis (cyclopentadienyl) alanes
(Spectro-)electrochemical characterisation of bridged donor-acceptor compounds
Macrocyclic Oligothiophene Bridged Perylene Bisimide Donor−Acceptor Dyads
Chapter III: Old Age; extant pictures hitherto unmentioned; missing and doubtful paintings
Electron delocalization in mixed-valence butadienediyl-bridged diruthenium complexes
On the mechanism of photoinduced electron transfer in bridged donor-acceptor systems : ferrocenophane-nileblue and rhodamine6G endcapping the DNA duplex
Fluorine donor bound electron spins as qubits
Fluorine donor bound electron spins as quibits
Nitrite, an Electron Donor for Anoxygenic Photosynthesis
Electrochemical redox properties of bridged and non‐bridged annulenediones
A hitherto unknown Meissonier
A Trithia‐Bridged N ‐Heterotriangulene: The Hitherto Missing Electron Donor
Donor‐Stabilized Monocarba‐Bridged Bis (cyclopentadienyl) alanes
(Spectro-)electrochemical characterisation of bridged donor-acceptor compounds
Macrocyclic Oligothiophene Bridged Perylene Bisimide Donor−Acceptor Dyads
Chapter III: Old Age; extant pictures hitherto unmentioned; missing and doubtful paintings
Electron delocalization in mixed-valence butadienediyl-bridged diruthenium complexes
On the mechanism of photoinduced electron transfer in bridged donor-acceptor systems : ferrocenophane-nileblue and rhodamine6G endcapping the DNA duplex
Fluorine donor bound electron spins as qubits
Fluorine donor bound electron spins as quibits
Nitrite, an Electron Donor for Anoxygenic Photosynthesis
Electrochemical redox properties of bridged and non‐bridged annulenediones