Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

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Abstract: A diaminocyclopentadienone ruthenium complex has proven to be a highly effective catalyst for the alkylation of indoles or ketones with poorly reactive alcohols. The catalyst is readily available, air and moisture stable and exhibits wide functional group tolerance. The environmentally benign procedure follows a borrowing hydrogen mechanism and requires no excess of either component. Various indoles and ketones are selectively monoalkylated in high yield.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols ; day:27 ; month:09 ; year:2023 ; extent:6
European journal of organic chemistry ; (27.09.2023) (gesamt 6)

Creator: Skowaisa, Steffen
Haak, Edgar

DOI: 10.1002/ejoc.202300707

URN: urn:nbn:de:101:1-2023092715335463219560

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 14.08.2025, 10:54 AM CEST

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Skowaisa, Steffen
Haak, Edgar

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Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

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Other Objects (12)

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Iridium‐Pyrazolato Complex Catalyzed Dehydrogenative Alkylation of Ketones and Arylacetonitriles with Primary Alcohols

The Murai Reaction: ortho-Directed Ruthenium-Catalyzed C–H Alkylation of Aromatic Ketones

Pd-Catalyzed Allylic Alkylation of Ketones

Indium-Catalyzed Reductive Alkylation of Indoles

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Pd-Catalyzed Allylic Alkylation of Ketones

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Chromium-Catalyzed Alkylation of Amines by Alcohols

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