Redox‐Neutral Dual Functionalization of Electron‐Deficient Alkenes
Abstract: Visible‐light photoredox catalysis has been utilized in a new multicomponent reaction forming β‐functionalized δ‐diketones under mild conditions in an operationally convenient manner. Single‐electron reduction of in situ generated carboxylic acid derivatives forms acyl radicals that react further via 1,2‐acylalkylation of olefins in an intermolecular, three‐components cascade reaction, giving valuable synthetic entities from readily available starting materials. A diverse set of substrates has been used, demonstrating robust methodology with broad substrate scope.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Redox‐Neutral Dual Functionalization of Electron‐Deficient Alkenes ; volume:23 ; number:31 ; year:2017 ; pages:7444-7447 ; extent:4
Chemistry - a European journal ; 23, Heft 31 (2017), 7444-7447 (gesamt 4)
- Urheber
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Pettersson, Fredrik
Bergonzini, Giulia
Cassani, Carlo
Wallentin, Carl‐Johan
- DOI
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10.1002/chem.201701589
- URN
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urn:nbn:de:101:1-2022092309005390919842
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:23 MESZ
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Beteiligte
- Pettersson, Fredrik
- Bergonzini, Giulia
- Cassani, Carlo
- Wallentin, Carl‐Johan
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