Structure formation in solution : ionic polymers and colloidal particles

This book is designed to critically review experimental findings on ionic polymers and colloidal particles and to prove a theoretical framework based on the Poisson-Boltzmann approach. Structure formation in ionic polymer solutions has attracted attention since the days of H. Staudinger and J. D. Bernal. An independent study on ionic colloidal dispersions with microscopy provided a compelling evidence of structure formation. Recent technical developments have made it possible to accumulate relevant information for both ionic polymers and colloidal particles in dilute systems. The outstanding phenomenon experimentally found is microscopic inhomogeneity in the solute distribution in macroscopically homogeneous systems.To account for the observation, the present authors have invoked the existence of the counterion-mediated attraction between similarly charged solute species, in addition to the widely accepted electrostatic repulsion. TOC:Dilute Solution of Flexible and Spherical Polyelectrolytes.- Colloidal Dispersions.- Effective Interaction in Ionic Polymer Solutions.- Viscometric Properties of Ionic Polymer Solutions and Colloidal Dispersion.- Computer Simulation and Phase Transition.- Repulsion-Only Assumption and Repulsion-Attraction Assumption

Location
Deutsche Nationalbibliothek Frankfurt am Main
ISBN
9783540252719
3540252711
Dimensions
24 cm
Extent
VIII, 350 S.
Language
Englisch
Notes
Ill., graph. Darst.
Literaturangaben

Classification
Physik
Keyword
Ionische Polymere
Polymerlösung
Strukturbildung
Boltzmann-Gleichung
Poisson-Gleichung
Dispersion
Kolloides System
Strukturbildung

Event
Veröffentlichung
(where)
Berlin, Heidelberg, New York
(who)
Springer
(when)
2005
Creator

Table of contents
Rights
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Last update
11.06.2025, 2:10 PM CEST

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Associated

Time of origin

  • 2005

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