Coordination vs. insertion: on the interaction of 5d‐transition metal carbonyl clusters with silver(I)
Abstract: The title silver(I) complex salts [Ag{Re2(CO)10}{Re(CO)5}2]+[Al(ORF)4]− (AgRe4; ORF=-OC(CF3)3) and [Ag{Ir4(CO)12}2]+[Al(ORF)4]− (AgIr8) form upon reaction of Ag+[Al(ORF)4]− and the transition metal carbonyls (TMCs) Re2(CO)10 and Ir4(CO)12 respectively. The solid-state structure of the AgRe4 cluster shows an unexpected asymmetric coordination motif, wherein the silver(I) cation has inserted into the Re−Re bond of one Re2(CO)10 moiety, while the other dirhenium carbonyl coordinates only over one metal atom towards the silver(I) cation. The AgIr8 cluster is formed by the edge-on coordination of two Ir4 tetrahedra and the silver cation in a D2 symmetric fashion with a torsion angle of 46.5°. QTAIM analysis shows bond paths between the silver atom and the nearby metal atoms in all cases, whereas only the non-inserted Re2(CO)10 moiety shows additional bond paths between the carbonyl ligands and the silver cation. In addition, the insertion of the Ag+ cation into the Re−Re bond in Re2(CO)10 removes the bond path between the two rhenium atoms. The EDA-NOCV analysis suggests an increase of the interaction energy between the silver(I) cation and the respective metal carbonyls from the metal centered transition metal carbonyl (TMC) donors W(CO)6
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Notes
-
Chemistry – a European journal. - 29, 34 (2023) , e202300908, ISSN: 1521-3765
- Event
-
Veröffentlichung
- (where)
-
Freiburg
- (who)
-
Universität
- (when)
-
2023
- Creator
- DOI
-
10.1002/chem.202300908
- URN
-
urn:nbn:de:bsz:25-freidok-2352235
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
25.03.2025, 1:48 PM CET
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Sellin, Malte
- Seiler, Matthis
- Krossing, Ingo
- Universität
Time of origin
- 2023
Other Objects (12)
Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide
Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett
Stable salts of heteroleptic iron carbonyl/nitrosyl cations
Homoleptic and heteroleptic early transition metal carbonyl complexes
Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations
Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen
Altering charges on heterobimetallic transition‐metal carbonyl clusters
Activation of the Ga(I) cation for bond activation: from oxidative additions into C−Cl and H−P bonds to reversible insertion into P4
Investigation of novel transition metal carbonyl cations and dinitrogen complexes
The inverted philosopher’s stone: how to turn silver to a base metal
Novel conducting salts for rechargeable lithium-ion batteries based on the difluorophosphato ligand : = Neuartige Leitsalze für Lithium-Ionen Akkumulatoren basierend auf dem Difluorphosphat-Liganden
Li[B(OCH(CF3)2)4] - Synthesis optimization and characterization of its Electrolytes : = Li[B(OCH(CF3)2)4] - Syntheseoptimierung und Charakterisierung dessen Elektrolyte
Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide
Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett
Stable salts of heteroleptic iron carbonyl/nitrosyl cations
Homoleptic and heteroleptic early transition metal carbonyl complexes
Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations
Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen
Altering charges on heterobimetallic transition‐metal carbonyl clusters
Activation of the Ga(I) cation for bond activation: from oxidative additions into C−Cl and H−P bonds to reversible insertion into P4
Investigation of novel transition metal carbonyl cations and dinitrogen complexes
The inverted philosopher’s stone: how to turn silver to a base metal
Novel conducting salts for rechargeable lithium-ion batteries based on the difluorophosphato ligand : = Neuartige Leitsalze für Lithium-Ionen Akkumulatoren basierend auf dem Difluorphosphat-Liganden
Li[B(OCH(CF3)2)4] - Synthesis optimization and characterization of its Electrolytes : = Li[B(OCH(CF3)2)4] - Syntheseoptimierung und Charakterisierung dessen Elektrolyte
Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide
Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett
Stable salts of heteroleptic iron carbonyl/nitrosyl cations
Homoleptic and heteroleptic early transition metal carbonyl complexes
Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations
Silver-Selenium complexes and phosphorus cations stabilised by weakly coordinating anions : = Silber-Selen Komplexe und Phosphorkationen stabilisiert durch schwach koordinierende Anionen
Altering charges on heterobimetallic transition‐metal carbonyl clusters
Activation of the Ga(I) cation for bond activation: from oxidative additions into C−Cl and H−P bonds to reversible insertion into P4
Investigation of novel transition metal carbonyl cations and dinitrogen complexes
The inverted philosopher’s stone: how to turn silver to a base metal
Novel conducting salts for rechargeable lithium-ion batteries based on the difluorophosphato ligand : = Neuartige Leitsalze für Lithium-Ionen Akkumulatoren basierend auf dem Difluorphosphat-Liganden