Amino Acid‐Based Dithiocarbamates as Efficient Intermediates for Diversity‐Oriented Synthesis of Thiazoles
Amino acid‐based dithiocarbamates were introduced as efficient intermediates for the synthesis of a diverse library of novel di‐ and tri‐substituted thiazoles via condensation with various reagents such as anhydrides, acyl halides, benzene sulfonyl chloride, trifluoromethanesulfonic anhydride, chloroethyl formate, and diethyl chlorophosphate. The utilities of adducts in further organic synthesis were confirmed by Sonogashira and oxidation reactions. In addition, reaction of aspartic acid‐based dithiocarbamates with anhydrides affords the corresponding fused 6,6a‐dihydrofuro[3,2‐d]thiazol‐5 (3aH)‐ones diastereoselectively in excellent yields.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Amino Acid‐Based Dithiocarbamates as Efficient Intermediates for Diversity‐Oriented Synthesis of Thiazoles ; volume:2020 ; number:38 ; year:2020 ; pages:6081-6084 ; extent:4
European journal of organic chemistry ; 2020, Heft 38 (2020), 6081-6084 (gesamt 4)
- Creator
- DOI
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10.1002/ejoc.202001050
- URN
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urn:nbn:de:101:1-2022070311373531850613
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:22 AM CEST
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Associated
- Ziyaei Halimehjani, Azim
- Khalesi, Maryam
- Breit, Bernhard
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A Highly Active Hydroformylation Catalyst Using a Self‐Assembling Bis ‐ N ‐Pyrrolyl Phosphine Ligand
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Rhodium‐Catalyzed Asymmetric Macrocyclization towards Crown Ethers Using Hydroamination of Bis (allenes)
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