Ligands with Two Monoanionic N,N‐Binding Sites: Synthesis and Coordination Chemistry
Abstract: Polytopic ligands have become ubiquitous in coordination chemistry because they grant access to a variety of mono‐ and polynuclear complexes of transition metals as well as rare‐earth and main‐group elements. Nitrogen‐based ditopic ligands, in which two monoanionic N,N‐binding sites are framed within one molecule, are of particular importance and are therefore the primary focus of this review. In detail, bis (amidine) s, bis (guanidine) s, bis (β‐diimine) s, bis (aminotroponimine) s, bis (pyrrolimine) s, and miscellaneous bis (N,N‐chelating) ligands are reviewed. In addition to the general synthetic protocols, the application of these ligands is discussed along with their coordination chemistry, the multifarious binding modes, and the ability of these ligands to bridge two (or more) metal (loids).
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Ligands with Two Monoanionic N,N‐Binding Sites: Synthesis and Coordination Chemistry ; volume:26 ; number:10 ; year:2020 ; pages:2099-2119 ; extent:21
Chemistry - a European journal ; 26, Heft 10 (2020), 2099-2119 (gesamt 21)
- Creator
- DOI
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10.1002/chem.201903442
- URN
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urn:nbn:de:101:1-2022060614305698275847
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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21.03.2025, 7:57 AM CET
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