Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process
Abstract: After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C) bond during the methanol‐to‐hydrocarbon (MTH) process has very recently been unveiled. However, the relevance of the “direct mechanism”‐derived molecules (that is, methyl acetate) during MTH, and subsequent transformation routes to the conventional hydrocarbon pool (HCP) species, are yet to be established. This important piece of the MTH chemistry puzzle is not only essential from a fundamental perspective, but is also important to maximize catalytic performance. The MTH process was probed over a commercially relevant H‐SAPO‐34 catalyst, using a combination of advanced solid‐state NMR spectroscopy and operando UV/Vis diffuse reflectance spectroscopy coupled to an on‐line mass spectrometer. Spectroscopic evidence is provided for the formation of (olefinic and aromatic) HCP species, which are indeed derived exclusively from the direct C−C bond‐containing acetyl group of methyl acetate. New mechanistic insights have been obtained from the MTH process, including the identification of hydrocarbon‐based co‐catalytic organic reaction centers.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process ; volume:57 ; number:27 ; year:2018 ; pages:8095-8099 ; extent:5
Angewandte Chemie / International edition. International edition ; 57, Heft 27 (2018), 8095-8099 (gesamt 5)
- Urheber
-
Dutta Chowdhury, Abhishek
Paioni, Alessandra Lucini
Houben, Klaartje
Whiting, Gareth T.
Baldus, Marc
Weckhuysen, Bert
- DOI
-
10.1002/anie.201803279
- URN
-
urn:nbn:de:101:1-2022081809202210065592
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:22 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Dutta Chowdhury, Abhishek
- Paioni, Alessandra Lucini
- Houben, Klaartje
- Whiting, Gareth T.
- Baldus, Marc
- Weckhuysen, Bert
Ähnliche Objekte (12)
Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process
Separation and Purification of Hydrocarbons with Porous Materials
Separation and Purification of Hydrocarbons with Porous Materials
Effect of Steaming on Waste‐Derived Zeolite ZSM‐5 as Methanol‐To‐Hydrocarbons Catalyst
Elucidating Zeolite Channel Geometry–Reaction Intermediate Relationships for the Methanol‐to‐Hydrocarbon Process
Thermally Stable TiO 2 ‐ and SiO 2 ‐Shell‐Isolated Au Nanoparticles for In Situ Plasmon‐Enhanced Raman Spectroscopy of Hydrogenation Catalysts
Carbon Pathways, Sodium‐Sulphur Promotion and Identification of Iron Carbides in Iron‐based Fischer‐Tropsch Synthesis
Visualizing the Structure, Composition and Activity of Single Catalyst Particles for Olefin Polymerization and Polyolefin Decomposition
Visualizing the Structure, Composition and Activity of Single Catalyst Particles for Olefin Polymerization and Polyolefin Decomposition
Crystal Phase Effects on the Gas‐Phase Ketonization of Small Carboxylic Acids over TiO 2 Catalysts
Unraveling the Homologation Reaction Sequence of the Zeolite‐Catalyzed Ethanol‐to‐Hydrocarbons Process
Unraveling the Homologation Reaction Sequence of the Zeolite‐Catalyzed Ethanol‐to‐Hydrocarbons Process
Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process
Separation and Purification of Hydrocarbons with Porous Materials
Separation and Purification of Hydrocarbons with Porous Materials
Effect of Steaming on Waste‐Derived Zeolite ZSM‐5 as Methanol‐To‐Hydrocarbons Catalyst
Elucidating Zeolite Channel Geometry–Reaction Intermediate Relationships for the Methanol‐to‐Hydrocarbon Process
Thermally Stable TiO 2 ‐ and SiO 2 ‐Shell‐Isolated Au Nanoparticles for In Situ Plasmon‐Enhanced Raman Spectroscopy of Hydrogenation Catalysts
Carbon Pathways, Sodium‐Sulphur Promotion and Identification of Iron Carbides in Iron‐based Fischer‐Tropsch Synthesis
Visualizing the Structure, Composition and Activity of Single Catalyst Particles for Olefin Polymerization and Polyolefin Decomposition
Visualizing the Structure, Composition and Activity of Single Catalyst Particles for Olefin Polymerization and Polyolefin Decomposition
Crystal Phase Effects on the Gas‐Phase Ketonization of Small Carboxylic Acids over TiO 2 Catalysts
Unraveling the Homologation Reaction Sequence of the Zeolite‐Catalyzed Ethanol‐to‐Hydrocarbons Process
Unraveling the Homologation Reaction Sequence of the Zeolite‐Catalyzed Ethanol‐to‐Hydrocarbons Process
Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process
Separation and Purification of Hydrocarbons with Porous Materials
Separation and Purification of Hydrocarbons with Porous Materials
Effect of Steaming on Waste‐Derived Zeolite ZSM‐5 as Methanol‐To‐Hydrocarbons Catalyst
Elucidating Zeolite Channel Geometry–Reaction Intermediate Relationships for the Methanol‐to‐Hydrocarbon Process
Thermally Stable TiO 2 ‐ and SiO 2 ‐Shell‐Isolated Au Nanoparticles for In Situ Plasmon‐Enhanced Raman Spectroscopy of Hydrogenation Catalysts
Carbon Pathways, Sodium‐Sulphur Promotion and Identification of Iron Carbides in Iron‐based Fischer‐Tropsch Synthesis
Visualizing the Structure, Composition and Activity of Single Catalyst Particles for Olefin Polymerization and Polyolefin Decomposition
Visualizing the Structure, Composition and Activity of Single Catalyst Particles for Olefin Polymerization and Polyolefin Decomposition
Crystal Phase Effects on the Gas‐Phase Ketonization of Small Carboxylic Acids over TiO 2 Catalysts
Unraveling the Homologation Reaction Sequence of the Zeolite‐Catalyzed Ethanol‐to‐Hydrocarbons Process