Investigations into Improved Electrochemical Performance of Sn Doped Hard Carbons as Negatives for Sodium‐Ion Batteries
Abstract: Hard carbons are the most suitable anode materials for practical sodium‐ion batteries (NIBs). Despite various studies, there is still significant scope for improvement in the understanding of the (de) sodiation mechanisms. Here, we study Sn incorporation in waste derived commercial and model sucrose derived hard carbons and its effect on the electrochemical performance. Sn incorporation leads to improved first cycle coulombic efficiency and capacity, specifically increase in the plateau capacity. An improvement from 220 mAh/g to 285 mAh/g and 325 mAh/g is respectively obtained for 7 % and 15 % Sn in hard carbon‐Sn composites (HC/Sn). Sn incorporation in both hard carbons has been shown to improve the electrochemical performance, notably achieving a synergy with capacities in excess of that expected from simple addition. For example, 7 % Sn additions tend to increase capacity by 25 %, twice that predicted from simple addition. X‐ray diffraction (XRD) studies show that the number of graphene layers in nano‐graphitic domains is reduced after Sn incorporation with no change in interlayer spacing. Full cells with commercial benchmark cathodes are also presented along with cost analysis of the Sn doping routes in this study to demonstrate the commercial viability of the strategy.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Investigations into Improved Electrochemical Performance of Sn Doped Hard Carbons as Negatives for Sodium‐Ion Batteries ; day:18 ; month:09 ; year:2023 ; extent:7
Batteries & supercaps ; (18.09.2023) (gesamt 7)
- Creator
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Tripathi, Abhinav
Murugesan, Chinnasamy
Naden, Aaron
Curran, Peter
Kavanagh, Chris M.
Condliffe, James M.
Armstrong, A. Robert
Irvine, John
- DOI
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10.1002/batt.202300225
- URN
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urn:nbn:de:101:1-2023091815180407283390
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:51 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Tripathi, Abhinav
- Murugesan, Chinnasamy
- Naden, Aaron
- Curran, Peter
- Kavanagh, Chris M.
- Condliffe, James M.
- Armstrong, A. Robert
- Irvine, John
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Solvothermal‐Derived S‐Doped Graphene as an Anode Material for Sodium‐Ion Batteries
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Fluorine-Doped Hard Carbon as the Advanced Performance Anode Material of Sodium-Ion Batteries
Hard Carbon Anode Materials for Sodium-ion Batteries
Spray‐coated Hard Carbon Composite Anodes for Sodium‐Ion Insertion
Fabrication of S,N-Doped Carbon-Coated SnS2/SnS Heterostructures Supported by Hollow Carbon Microspheres for Sodium-Ion Storage
Glyoxylic‐Acetal‐Based Electrolytes for Sodium‐Ion Batteries and Sodium‐Ion Capacitors
Hard‐Carbon Anodes for Sodium‐Ion Batteries: Recent Status and Challenging Perspectives
Designing Tin and Hard Carbon Architecture for Stable Sodium‐Ion Battery Anode
Sodium-ion batteries, Volume 2
Sodium-ion batteries, Volume 1
Solvothermal‐Derived S‐Doped Graphene as an Anode Material for Sodium‐Ion Batteries
Stabilising Cobalt Sulphide Nanocapsules with Nitrogen-Doped Carbon for High-Performance Sodium-Ion Storage
Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries
Fluorine-Doped Hard Carbon as the Advanced Performance Anode Material of Sodium-Ion Batteries
Hard Carbon Anode Materials for Sodium-ion Batteries
Spray‐coated Hard Carbon Composite Anodes for Sodium‐Ion Insertion
Fabrication of S,N-Doped Carbon-Coated SnS2/SnS Heterostructures Supported by Hollow Carbon Microspheres for Sodium-Ion Storage
Glyoxylic‐Acetal‐Based Electrolytes for Sodium‐Ion Batteries and Sodium‐Ion Capacitors
Hard‐Carbon Anodes for Sodium‐Ion Batteries: Recent Status and Challenging Perspectives
Designing Tin and Hard Carbon Architecture for Stable Sodium‐Ion Battery Anode
Sodium-ion batteries, Volume 2
Sodium-ion batteries, Volume 1
Solvothermal‐Derived S‐Doped Graphene as an Anode Material for Sodium‐Ion Batteries
Stabilising Cobalt Sulphide Nanocapsules with Nitrogen-Doped Carbon for High-Performance Sodium-Ion Storage