Recent advances in dynamic covalent bond-based shape memory polymers

Abstract: Dynamic covalent bond-based shape memory polymers (DCB-SMPs) are one of most important SMPs which have a wide potential application prospect. Different from common strong covalent bonds, DCBs own relatively weak bonding energy, similarly to the supramolecular interactions of noncovalent bonds, and can dynamically combine and dissociate these bonds. DCB-SMP solids, which can be designed to respond for different stimuli, can provide excellent self-healing, good reprocessability, and high mechanical performance, because DCBs can obtain dynamic cross-linking without sacrificing ultrahigh fixing rates. Furthermore, besides DCB-SMP solids, DCB-SMP hydrogels with responsiveness to various stimuli also have been developed recently, which have special biocompatible soft/wet states. Particularly, DCB-SMPs can be combined with emerging 3D-printing techniques to design various original shapes and subsequently complex shape recovery. This review has summarized recent research studies about SMPs based on various DCBs including DCB-SMP solids, DCB-SMP hydrogels, and the introduction of new 3D-printing techniques using them. Last but not least, the advantages/disadvantages of different DCB-SMPs have been analyzed via polymeric structures and the future development trends in this field have been predicted.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Recent advances in dynamic covalent bond-based shape memory polymers ; volume:22 ; number:1 ; year:2022 ; pages:285-300 ; extent:16
e-Polymers ; 22, Heft 1 (2022), 285-300 (gesamt 16)

Urheber
Peng, Shuyi
Sun, Ye
Ma, Chunming
Duan, Gaigai
Liu, Zhenzhong
Ma, Chunxin

DOI
10.1515/epoly-2022-0032
URN
urn:nbn:de:101:1-2022071614055802741675
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:31 MESZ

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Beteiligte

  • Peng, Shuyi
  • Sun, Ye
  • Ma, Chunming
  • Duan, Gaigai
  • Liu, Zhenzhong
  • Ma, Chunxin

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