High‐Temperature Pyrolysis Regulation of Schiff Base 3 d Coordination Clusters for Electrochemical Application
Abstract: 3Dtransition metal coordination clusters, as structurally diverse and designable metal‐organic hybrid systems, enable deliberate modulation of active sites and bridging motifs within their structural kernels, making them ideal precursors for tailored nanostructures via pyrolysis. Through precise control over metal/organic ratios, the composition, spatial configuration, and electronic structure of derived nanomaterials can be effectively regulated, holding great promise for establishing structure‐property relations and achieving optimized functional materials. In this review, nanostructures of Schiff base coordination clusters to control and optimize electrochemical energy storage/conversion performances. Specifically, coordination framework engineered clusters have been pyrolyzed into electrode materials for supercapacitors and electrocatalysts for oxygen/hydrogen evolution reactions, exhibiting significantly enhanced capacitance and catalytic activity. Furthermore, perspectives are provided on employing molecular‐level design principles of clusters in combination with pyrolysis optimization to develop next‐generation customized energy systems. Additional investigation into structure‐performance interdependencies will shed light on targeted optimization of cluster‐derived nanostructures.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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High‐Temperature Pyrolysis Regulation of Schiff Base 3 d Coordination Clusters for Electrochemical Application ; day:31 ; month:01 ; year:2025 ; extent:7
ChemElectroChem ; (31.01.2025) (gesamt 7)
- Creator
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Wang, Zhao
Rong, Hongwei
Yang, Xixian
Xi, Xiaoxue
Chen, Xueli
Li, Yuebin
Yi, Renshuai
Peng, Xu
- DOI
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10.1002/celc.202400453
- URN
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urn:nbn:de:101:1-2502031307058.937187557858
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:32 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Wang, Zhao
- Rong, Hongwei
- Yang, Xixian
- Xi, Xiaoxue
- Chen, Xueli
- Li, Yuebin
- Yi, Renshuai
- Peng, Xu
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