Preparation of PVDF-HFP/CB/Ni nanocomposite films for piezoelectric energy harvesting

Abstract: As a representative flexible piezoelectric polymer, polyvinylidene fluoride (PVDF) and its copolymers have been widely used in energy harvesters and piezoelectric sensors. In this work, hybrid nanocomposite films were prepared by adding a small amount of carbon black (CB) and Ni nanoparticles to the poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) matrix using the solution casting method, followed by stretching and poling to increase the electroactive β-phase content. The results show that the hybrid fillers consisting of 0.3 wt% CB and 0.1 wt% Ni nanoparticles exhibit the best piezoelectric performance. The maximum output voltage of the PVDF-HFP/CB/Ni films reaches 3.5 V under 1 mm micro-vibration, which is 75% higher than that of pure PVDF-HFP films. Characterization results by X-ray diffraction analysis, Fourier-transform infrared spectrometry, and differential scanning calorimeter analysis show that the hybrid fillers are more effective in promoting the phase transformation from the α-phase to the β-phase in the matrix due to synergistic effect.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Preparation of PVDF-HFP/CB/Ni nanocomposite films for piezoelectric energy harvesting ; volume:62 ; number:1 ; year:2023 ; extent:15
Reviews on advanced materials science ; 62, Heft 1 (2023) (gesamt 15)

Urheber
Wang, Yang
Lei, Dan
Wu, Liangke
Hu, Ning
Ning, Huiming
Alamusi
Liu, Yaolu

DOI
10.1515/rams-2023-0146
URN
urn:nbn:de:101:1-2023121514330435840807
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:26 MESZ

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Beteiligte

  • Wang, Yang
  • Lei, Dan
  • Wu, Liangke
  • Hu, Ning
  • Ning, Huiming
  • Alamusi
  • Liu, Yaolu

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