Control of Polar/Antipolar Layered Organic Semiconductors by the Odd‐Even Effect of Alkyl Chain

Abstract: Some rodlike organic molecules exhibit exceptionally high layered crystallinity when composed of a link between π‐conjugated backbone (head) and alkyl chain (tail). These molecules are aligned side‐by‐side unidirectionally to form self‐organized polar monomolecular layers, providing promising 2D materials and devices. However, their interlayer stacking arrangements have never been tunable, preventing the unidirectional arrangements of molecules in whole crystals. Here, it is demonstrated that polar/antipolar interlayer stacking can be systematically controlled by the alkyl carbon number n, when the molecules are designed to involve effectively weakened head‐to‐head affinity. They exhibit remarkable odd–even effect in the interlayer stacking: alternating head‐to‐head and tail‐to‐tail (antipolar) arrangement in odd‐n crystals, and uniform head‐to‐tail (polar) arrangement in even‐n crystals. The films show excellent field‐effect transistor characteristics presenting unique polar/antipolar dependence and considerably improved subthreshold swing in the polar films. Additionally, the polar films present enhanced second‐order nonlinear optical response along normal to the film plane. These findings are key for creating polarity‐controlled optoelectronic materials and devices.

Angaben zum Objekt

• Standort: Deutsche Nationalbibliothek Frankfurt am Main
• Umfang: Online-Ressource
• Sprache: Englisch

Verweise und Beziehungen

• Erschienen in: Control of Polar/Antipolar Layered Organic Semiconductors by the Odd‐Even Effect of Alkyl Chain ; day:25 ; month:01 ; year:2024 ; extent:11 ; Advanced science ; (25.01.2024) (gesamt 11)

Beteiligte, Orts- und Zeitangaben

• Urheber: Inoue, Satoru ; Higashino, Toshiki ; Nikaido, Kiyoshi ; Miyata, Ryo ; Matsuoka, Satoshi ; Tanaka, Mutsuo ; Tsuzuki, Seiji ; Horiuchi, Sachio ; Kondo, Ryusuke ; Sagayama, Ryoko ; Kumai, Reiji ; Sekine, Daiki ; Koyanagi, Takayoshi ; Matsubara, Masakazu ; Hasegawa, Tatsuo

Weitere Informationen

• DOI: 10.1002/advs.202308270
• URN: urn:nbn:de:101:1-2024012514252732333561
• Rechteinformation: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Letzte Aktualisierung: 15.08.2025, 07:37 MESZ