Catechol Thioesters: Ligands for Hierarchically Formed Lithium‐Bridged Titanium (IV) Helicates and Helicate‐Based Switches
Abstract: The thioester moiety is introduced as a lithium binding unit for the hierarchical formation of titanium (IV) catecholate‐based lithium‐bridged helicates. In solution, the coordination compounds show a monomer–dimer equilibrium which —in comparison to the oxo esters— is significantly shifted towards the monomers. In addition, the influence of the thioester side chain on the dimerization behavior is investigated and an expansible/compressible molecular switch is synthesized. In the latter case expansion and compression are performed reversibly in methanol, whereas in DMSO spontaneous expansion occurs.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Catechol Thioesters: Ligands for Hierarchically Formed Lithium‐Bridged Titanium (IV) Helicates and Helicate‐Based Switches ; volume:26 ; number:17 ; year:2020 ; pages:3829-3833 ; extent:5
Chemistry - a European journal ; 26, Heft 17 (2020), 3829-3833 (gesamt 5)
- Creator
- DOI
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10.1002/chem.201905212
- URN
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urn:nbn:de:101:1-2022060807102764679514
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
Data provider
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Kwamen, A. Carel N.
- de Macedo, Gilles S.
- Wiederhold, Constanze
- Oppel, Iris M.
- Albrecht, Markus
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