Preparation of novel acyl pyrazoles and triazoles by means of oxidative functionalization reactions
Abstract: Novel acyl pyrazoles and acyl triazoles have been prepared by means of the oxidative amidation of aldehydes in the presence of the requisite azole. Yields range from modest to good in both cases, and some limitations of the substrate scope have been discovered. Acyl pyrazoles were prepared by treatment of a mixture of aldehyde and pyrazole with an oxoammonium salt bearing the nitrate anion. In the case of acyl triazoles, the oxidative functionalization was performed using sodium persulfate as a terminal oxidant in the presence of a catalytic quantity of a nitroxide.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Preparation of novel acyl pyrazoles and triazoles by means of oxidative functionalization reactions ; volume:29 ; number:1 ; year:2023 ; extent:8
Heterocyclic communications ; 29, Heft 1 (2023) (gesamt 8)
- Creator
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Wadey, Geoffrey P.
Doherty, Katrina E.
Sandoval, Arturo León
Leadbeater, Nicholas E.
- DOI
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10.1515/hc-2022-0158
- URN
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urn:nbn:de:101:1-2023020813131467663979
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:59 AM CEST
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Associated
- Wadey, Geoffrey P.
- Doherty, Katrina E.
- Sandoval, Arturo León
- Leadbeater, Nicholas E.
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