Aqueous Photocatalytic Oxidation of Thioethers with Polydiacetylene Micelle Nanoreactors

Abstract: A semi‐heterogeneous photocatalytic system was assembled through encapsulation of a lipophilic porphyrin in stabilized polydiacetylene micelles. The colloidal nanohybrid catalyst was valorized in the aerobic photo‐oxidation of sulfides to the corresponding sulfoxides. Micelles behaved as nanoreactors by creating a favorable environment for the photo‐activation of oxygen nearby thioethers and subsequent sulfoxidation. The process operates selectively under visible light and air atmosphere, with low catalytic loading and in water as the only solvent.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Aqueous Photocatalytic Oxidation of Thioethers with Polydiacetylene Micelle Nanoreactors ; day:01 ; month:11 ; year:2024 ; extent:8
ChemSusChem ; (01.11.2024) (gesamt 8)

Creator
Tchuiteng Kouatchou, Joel Armel
Huber, Gaspard
Moinard, Morgane
Gravel, Edmond
Doris, Eric

DOI
10.1002/cssc.202401395
URN
urn:nbn:de:101:1-2411021307166.117718688036
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:36 AM CEST

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Associated

  • Tchuiteng Kouatchou, Joel Armel
  • Huber, Gaspard
  • Moinard, Morgane
  • Gravel, Edmond
  • Doris, Eric

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