Chirality Sensing and Size Discrimination of Anions by Macrotricyclic Cyclen–Disodium Complexes †
Abstract: Two macrotricyclic ligands composed of two face‐to‐face octadentate metal chelates were synthesized. These cage‐shaped disodium complexes had special recognition ability for various counter anions. Specific chiral dicarboxylates bound to the complexes within the cavity and exhibited chirality induction properties. For instance, N‐Boc‐Asp dianion strongly induced circular dichroism (CD) signals, but N‐Boc‐Glu dianion, which is one carbon longer, did not.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Chirality Sensing and Size Discrimination of Anions by Macrotricyclic Cyclen–Disodium Complexes † ; volume:3 ; number:6 ; year:2014 ; pages:238-241 ; extent:4
ChemistryOpen ; 3, Heft 6 (2014), 238-241 (gesamt 4)
- Creator
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Ito, Hiroshi
Shinoda, Satoshi
- DOI
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10.1002/open.201402049
- URN
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urn:nbn:de:101:1-2023011407461190040755
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Associated
- Ito, Hiroshi
- Shinoda, Satoshi
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