Stochastic Simulation of Controlled Radical Polymerization Forming Dendritic Hyperbranched Polymers
Abstract: Stochastic simulation of the formation process of hyperbranched polymers (HBPs) based on the reversible deactivation radical polymerization (RDRP) using a branch‐inducing monomer, evolmer, has been carried out. The simulation program successfully reproduced the change of dispersities (Đs) during the polymerization process. Furthermore, the simulation suggested that the observed Đs (=1.5–2) are due to the distribution of the number of branches instead of undesired side reactions, and that the branch structures are well controlled. In addition, the analysis of the polymer structure reveals that the majority of HBPs have structures close to the ideal one. The simulation also suggested the slight dependence of branch density on molecular weight, which was experimentally confirmed by synthesizing HBPs with an evolmer having phenyl group.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Stochastic Simulation of Controlled Radical Polymerization Forming Dendritic Hyperbranched Polymers ; day:14 ; month:06 ; year:2023 ; extent:8
Angewandte Chemie / International edition. International edition ; (14.06.2023) (gesamt 8)
- Urheber
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Tosaka, Masatoshi
Takeuchi, Hinako
Kibune, Masato
Tong, Tianxiang
Zhu, Nanyi
Yamago, Shigeru
- DOI
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10.1002/anie.202305127
- URN
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urn:nbn:de:101:1-2023061515055093731261
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 10:49 MESZ
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Beteiligte
- Tosaka, Masatoshi
- Takeuchi, Hinako
- Kibune, Masato
- Tong, Tianxiang
- Zhu, Nanyi
- Yamago, Shigeru
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