Electronic Character of α,3‐Dehydrotoluene Intermediates Generated from Isolable Allenyne‐Containing Substrates
Abstract: We report here the generation of α,3‐dehydrotoluenes, a relatively rare subset of reactive intermediates of the dehydroaromatic family, from isolable allenynes. The substructure motif in the allenyne substrates is distinct from, and complementary to, those found in Myers‐Saito/Schmittel‐type cycloisomerizations. The reactions reported here give rise to product profiles that provide insight about the electronic nature (i.e., diradical vs. zwitterion vs. cyclic allene) of the particular isomeric DHT (s) that is (are) produced under different reaction conditions differing most significantly in the polarity of the reaction solvent. One example also revealed previously unobserved carbene‐like reactivity of the DHT.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Electronic Character of α,3‐Dehydrotoluene Intermediates Generated from Isolable Allenyne‐Containing Substrates ; day:29 ; month:08 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (29.08.2022) (gesamt 1)
- Creator
-
Xu, Qian
Hoye, Thomas R.
- DOI
-
10.1002/anie.202207510
- URN
-
urn:nbn:de:101:1-2022083015422931985683
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:29 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Xu, Qian
- Hoye, Thomas R.
Other Objects (12)
Electronic Character of α,3‐Dehydrotoluene Intermediates Generated from Isolable Allenyne‐Containing Substrates
Action research plan: a methodology to examine the impact of artificial intelligence (AI) on the cognitive abilities of university students
Knowledge Diffusion within the Datang Sock Manufacturing Cluster in China
The stability of bifurcating steady states for a spatially heterogeneous cooperative system with cross-diffusion
Knowledge Diffusion within the Datang Sock Manufacturing Cluster in China
Single nucleotide polymorphisms and sporadic colorectal cancer susceptibility: a field synopsis and meta-analysis
Machine Learning Orchestrating the Materials Discovery and Performance Optimization of Redox Flow Battery
Exploring the medical decision-making patterns and influencing factors among the general Chinese public: a binary logistic regression analysis
A note on Hardy’s inequality
What impact do personality traits have on self-perception of dental aesthetics?
On a strengthened version of Hardy’s inequality
Innate immune responses in RNA viral infection
Electronic Character of α,3‐Dehydrotoluene Intermediates Generated from Isolable Allenyne‐Containing Substrates
Action research plan: a methodology to examine the impact of artificial intelligence (AI) on the cognitive abilities of university students
Knowledge Diffusion within the Datang Sock Manufacturing Cluster in China
The stability of bifurcating steady states for a spatially heterogeneous cooperative system with cross-diffusion
Knowledge Diffusion within the Datang Sock Manufacturing Cluster in China
Single nucleotide polymorphisms and sporadic colorectal cancer susceptibility: a field synopsis and meta-analysis
Machine Learning Orchestrating the Materials Discovery and Performance Optimization of Redox Flow Battery
Exploring the medical decision-making patterns and influencing factors among the general Chinese public: a binary logistic regression analysis
A note on Hardy’s inequality
What impact do personality traits have on self-perception of dental aesthetics?
On a strengthened version of Hardy’s inequality
Innate immune responses in RNA viral infection
Electronic Character of α,3‐Dehydrotoluene Intermediates Generated from Isolable Allenyne‐Containing Substrates
Action research plan: a methodology to examine the impact of artificial intelligence (AI) on the cognitive abilities of university students
Knowledge Diffusion within the Datang Sock Manufacturing Cluster in China
The stability of bifurcating steady states for a spatially heterogeneous cooperative system with cross-diffusion
Knowledge Diffusion within the Datang Sock Manufacturing Cluster in China
Single nucleotide polymorphisms and sporadic colorectal cancer susceptibility: a field synopsis and meta-analysis
Machine Learning Orchestrating the Materials Discovery and Performance Optimization of Redox Flow Battery
Exploring the medical decision-making patterns and influencing factors among the general Chinese public: a binary logistic regression analysis
A note on Hardy’s inequality
What impact do personality traits have on self-perception of dental aesthetics?
On a strengthened version of Hardy’s inequality