Barrierless Electron Transfer in a Photosynthetic Reaction Center Model
Abstract: Vibrational spectroscopy is the ultimate tool to reveal whether any donor‐acceptor system is truly delocalized and therefore characterized by a single‐welled potential energy surface, or if it is marginally localized with a barrier that defines two minima. Our femtosecond IR absorption investigations on cyanide‐bridged mixed valence systems show a broad, intense and downshifted CN vibration signature, revealing, for the first time, an asymmetric, fully delocalized Class III photoinduced mixed valence system.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Barrierless Electron Transfer in a Photosynthetic Reaction Center Model ; day:21 ; month:02 ; year:2025 ; extent:7
Angewandte Chemie / International edition. International edition ; (21.02.2025) (gesamt 7)
- Urheber
- DOI
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10.1002/anie.202422633
- URN
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urn:nbn:de:101:1-2502221318486.452441598751
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:27 MESZ
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Beteiligte
- Ullrich, Tobias
- Ramírez‐Wierzbicki, Ivana
- Slep, Leonardo D.
- Cadranel, Alejandro
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