Barrierless Electron Transfer in a Photosynthetic Reaction Center Model
Abstract: Vibrational spectroscopy is the ultimate tool to reveal whether any donor‐acceptor system is truly delocalized and therefore characterized by a single‐welled potential energy surface, or if it is marginally localized with a barrier that defines two minima. Our femtosecond IR absorption investigations on cyanide‐bridged mixed valence systems show a broad, intense and downshifted CN vibration signature, revealing, for the first time, an asymmetric, fully delocalized Class III photoinduced mixed valence system.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Barrierless Electron Transfer in a Photosynthetic Reaction Center Model ; day:21 ; month:02 ; year:2025 ; extent:7
Angewandte Chemie / International edition. International edition ; (21.02.2025) (gesamt 7)
- Creator
- DOI
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10.1002/anie.202422633
- URN
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urn:nbn:de:101:1-2502221318486.452441598751
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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2025-08-15T07:27:26+0200
Data provider
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Ullrich, Tobias
- Ramírez‐Wierzbicki, Ivana
- Slep, Leonardo D.
- Cadranel, Alejandro
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Heteronuclear spin-torch experiments on photosynthetic reaction centers
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Modeling long-range proton transfer : new developments and application to the photosynthetic bacterial reaction center
Pulsed and transient electron paramagnetic resonance spectroscopy on light induced radical pairs in photosynthetic reaction centers
Tuning Electron‐Transfer Driving Force in Photosynthetic Special Pair Models
Barrierless Electron Transfer in a Photosynthetic Reaction Center Model
Energetics of electron and proton transfer in photosynthetic reaction centers
Reaction centers of photosynthetic bacteria
Novel porphyrin amino acids as building blocks for artificial photosynthetic reaction centers : photoinduced energy and electron transfer
Novel porphyrin amino acids as building blocks for artificial photosynthetic reaction centers : photoinduced energy and electron transfer
Electron paramagnetic resonance at 94 GHz : methodological developments and studies of photosynthetic reaction centers
Heteronuclear spin-torch experiments on photosynthetic reaction centers
A spectroscopic study of the energy landscape of proteins : electron transfer in photosynthetic reaction centers and ligand binding to heme proteins
Modeling long-range proton transfer : new developments and application to the photosynthetic bacterial reaction center
Modeling long-range proton transfer : new developments and application to the photosynthetic bacterial reaction center
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