Direct and Regioselective Di‐α‐fucosylation on the Secondary Rim of β‐Cyclodextrin
Abstract: A straightforward glycosylation method is described to regio‐ and stereoselectively introduce two α‐l‐fucose moieties directly to the secondary rim of β‐cyclodextrin. Using NMR and MS fragmentation studies, the nonasaccharide structure was determined, which was also visualized using molecular dynamics simulations. The reported glycosylation method proved to be robust on gram‐scale, and may be generally applied to directly glycosylate β‐cyclodextrins to make well‐defined multivalent glycoclusters.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Direct and Regioselective Di‐α‐fucosylation on the Secondary Rim of β‐Cyclodextrin ; volume:25 ; number:27 ; year:2019 ; pages:6722-6727 ; extent:6
Chemistry - a European journal ; 25, Heft 27 (2019), 6722-6727 (gesamt 6)
- Creator
-
Verkhnyatskaya, Stella A.
de Vries, Alex H.
Douma‐de Vries, Elmatine
Sneep, Renze J. L.
Walvoort, Marthe T. C.
- DOI
-
10.1002/chem.201806090
- URN
-
urn:nbn:de:101:1-2022072411155911555983
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
14.08.2023, 3:54 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Verkhnyatskaya, Stella A.
- de Vries, Alex H.
- Douma‐de Vries, Elmatine
- Sneep, Renze J. L.
- Walvoort, Marthe T. C.
Other Objects (12)
Direct and Regioselective Di‐α‐fucosylation on the Secondary Rim of β‐Cyclodextrin
Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
Lysosomal Targeting of β‐Cyclodextrin
![Konjugate bioaktiver Peptide mit β-Cyclodextrin [Beta-Cyclodextrin]](/assets/placeholder/searchResultMediaNoDigitisedMedia.png)
Konjugate bioaktiver Peptide mit β-Cyclodextrin [Beta-Cyclodextrin]
Regioselektive Funktionalisierung von Stärke und β-Cyclodextrin [Beta-Cyclodextrin]
Strukturelle Eigenschaften und chemische Modifizierungen von β-Cyclodextrin [Beta-Cyclodextrin]
Synthese von Rezeptormolekülen auf Basis von β-Cyclodextrin [Beta-Cyclodextrin]
SYNTHESIS OF NEW FLUORESCENT β-CYCLODEXTRIN SENSOR
Biofilm-based biocatalysis for β-cyclodextrin production by the surface-display of β-cyclodextrin glycosyltransferase in Bacillus subtilis
β-Cyclodextrin as Supramolecular Catalyst in Organic Synthesis
Entfernung aromatischer Umweltschadstoffe aus Wasser durch Adsorption an immobilisiertes β-Cyclodextrin [Beta-Cyclodextrin]
Formation of β-cyclodextrin complexes in an anhydrous environment
Direct and Regioselective Di‐α‐fucosylation on the Secondary Rim of β‐Cyclodextrin
Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
Lysosomal Targeting of β‐Cyclodextrin
Konjugate bioaktiver Peptide mit β-Cyclodextrin [Beta-Cyclodextrin]
Regioselektive Funktionalisierung von Stärke und β-Cyclodextrin [Beta-Cyclodextrin]
Strukturelle Eigenschaften und chemische Modifizierungen von β-Cyclodextrin [Beta-Cyclodextrin]
Synthese von Rezeptormolekülen auf Basis von β-Cyclodextrin [Beta-Cyclodextrin]
SYNTHESIS OF NEW FLUORESCENT β-CYCLODEXTRIN SENSOR
Biofilm-based biocatalysis for β-cyclodextrin production by the surface-display of β-cyclodextrin glycosyltransferase in Bacillus subtilis
β-Cyclodextrin as Supramolecular Catalyst in Organic Synthesis
Entfernung aromatischer Umweltschadstoffe aus Wasser durch Adsorption an immobilisiertes β-Cyclodextrin [Beta-Cyclodextrin]
Formation of β-cyclodextrin complexes in an anhydrous environment
Direct and Regioselective Di‐α‐fucosylation on the Secondary Rim of β‐Cyclodextrin
Space filling of β-cyclodextrin and β-cyclodextrin derivatives by volatile hydrophobic guests
Lysosomal Targeting of β‐Cyclodextrin
Konjugate bioaktiver Peptide mit β-Cyclodextrin [Beta-Cyclodextrin]
Regioselektive Funktionalisierung von Stärke und β-Cyclodextrin [Beta-Cyclodextrin]
Strukturelle Eigenschaften und chemische Modifizierungen von β-Cyclodextrin [Beta-Cyclodextrin]
Synthese von Rezeptormolekülen auf Basis von β-Cyclodextrin [Beta-Cyclodextrin]
SYNTHESIS OF NEW FLUORESCENT β-CYCLODEXTRIN SENSOR
Biofilm-based biocatalysis for β-cyclodextrin production by the surface-display of β-cyclodextrin glycosyltransferase in Bacillus subtilis
β-Cyclodextrin as Supramolecular Catalyst in Organic Synthesis
Entfernung aromatischer Umweltschadstoffe aus Wasser durch Adsorption an immobilisiertes β-Cyclodextrin [Beta-Cyclodextrin]