Enantioselective Photochemical Organocascade Catalysis
Abstract: Reported herein is a photochemical cascade process that combines the excited‐state and ground‐state reactivity of chiral organocatalytic intermediates. This strategy directly converts racemic cyclopropanols and α,β‐unsaturated aldehydes into stereochemically dense cyclopentanols with exquisite stereoselectivity. Mechanistic investigations have enabled elucidating the origin of the stereoconvergence, which is governed by a kinetic resolution process.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Enantioselective Photochemical Organocascade Catalysis ; volume:130 ; number:4 ; year:2018 ; pages:1080-1084 ; extent:5
Angewandte Chemie ; 130, Heft 4 (2018), 1080-1084 (gesamt 5)
- Urheber
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Woźniak, Łukasz
Magagnano, Giandomenico
Melchiorre, Paolo
- DOI
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10.1002/ange.201711397
- URN
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urn:nbn:de:101:1-2022081706372763058981
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 15.08.2025, 07:21 MESZ
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Beteiligte
- Woźniak, Łukasz
- Magagnano, Giandomenico
- Melchiorre, Paolo
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