Enantioselective Photochemical Organocascade Catalysis

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Abstract: Reported herein is a photochemical cascade process that combines the excited‐state and ground‐state reactivity of chiral organocatalytic intermediates. This strategy directly converts racemic cyclopropanols and α,β‐unsaturated aldehydes into stereochemically dense cyclopentanols with exquisite stereoselectivity. Mechanistic investigations have enabled elucidating the origin of the stereoconvergence, which is governed by a kinetic resolution process.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Enantioselective Photochemical Organocascade Catalysis ; volume:130 ; number:4 ; year:2018 ; pages:1080-1084 ; extent:5
Angewandte Chemie ; 130, Heft 4 (2018), 1080-1084 (gesamt 5)

Creator: Woźniak, Łukasz
Magagnano, Giandomenico
Melchiorre, Paolo

DOI: 10.1002/ange.201711397

URN: urn:nbn:de:101:1-2022081706372763058981

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:21 AM CEST

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Woźniak, Łukasz
Magagnano, Giandomenico
Melchiorre, Paolo

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