Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes
Abstract: Nickel‐catalyzed ipso‐borylations and silylations of aldehydes are described for the first time. The new functional‐group interconversion protocol is characterized by its scalability, functional‐group tolerance and wide substrate scope, including examples of late‐stage functionalization of complex molecules. The key for the successful reaction outcome is the use of a ketone as a hydride acceptor that intercepts the nickel hydride to undergo a reductive pathway, thus allowing formation of the desired C−B and C−Si bonds.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes ; volume:26 ; number:2 ; year:2020 ; pages:423-427 ; extent:5
Chemistry - a European journal ; 26, Heft 2 (2020), 423-427 (gesamt 5)
- Urheber
- DOI
-
10.1002/chem.201904842
- URN
-
urn:nbn:de:101:1-2022060809150381943893
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:23 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Srimontree, Watchara
- Guo, Lin
- Rueping, Magnus
Ähnliche Objekte (12)
Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes
Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
Facet‐Controlled Synthetic Strategy of Cu 2 O‐Based Crystals for Catalysis and Sensing
The Correlation Between Mindfulness, Decentering, and Psychological Problems: A Structural Equation Modeling Meta-Analysis
Nanocrystal Facets: Facet‐Controlled Synthetic Strategy of Cu 2 O‐Based Crystals for Catalysis and Sensing (Adv. Sci. 10/2015)
Recent advances in solid–liquid triboelectric nanogenerator technologies, affecting factors, and applications
Photoelectrochemical oxidative C(sp3)−H borylation of unactivated hydrocarbons
Optimize or satisfice in engineering design?
Nacre-inspired composites with different macroscopic dimensions: strategies for improved mechanical performance and applications
Biomimetic “Cactus Spine” with Hierarchical Groove Structure for Efficient Fog Collection
Stereospecific Nickel-Catalyzed Borylation of Secondary Benzyl Pivalates
Research on Water Resource Problems of Capital Economic Circle Based on Circular Economy
Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes
Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
Facet‐Controlled Synthetic Strategy of Cu 2 O‐Based Crystals for Catalysis and Sensing
The Correlation Between Mindfulness, Decentering, and Psychological Problems: A Structural Equation Modeling Meta-Analysis
Nanocrystal Facets: Facet‐Controlled Synthetic Strategy of Cu 2 O‐Based Crystals for Catalysis and Sensing (Adv. Sci. 10/2015)
Recent advances in solid–liquid triboelectric nanogenerator technologies, affecting factors, and applications
Photoelectrochemical oxidative C(sp3)−H borylation of unactivated hydrocarbons
Optimize or satisfice in engineering design?
Nacre-inspired composites with different macroscopic dimensions: strategies for improved mechanical performance and applications
Biomimetic “Cactus Spine” with Hierarchical Groove Structure for Efficient Fog Collection
Stereospecific Nickel-Catalyzed Borylation of Secondary Benzyl Pivalates
Research on Water Resource Problems of Capital Economic Circle Based on Circular Economy
Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes
Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
Facet‐Controlled Synthetic Strategy of Cu 2 O‐Based Crystals for Catalysis and Sensing
The Correlation Between Mindfulness, Decentering, and Psychological Problems: A Structural Equation Modeling Meta-Analysis
Nanocrystal Facets: Facet‐Controlled Synthetic Strategy of Cu 2 O‐Based Crystals for Catalysis and Sensing (Adv. Sci. 10/2015)
Recent advances in solid–liquid triboelectric nanogenerator technologies, affecting factors, and applications
Photoelectrochemical oxidative C(sp3)−H borylation of unactivated hydrocarbons
Optimize or satisfice in engineering design?
Nacre-inspired composites with different macroscopic dimensions: strategies for improved mechanical performance and applications
Biomimetic “Cactus Spine” with Hierarchical Groove Structure for Efficient Fog Collection
Stereospecific Nickel-Catalyzed Borylation of Secondary Benzyl Pivalates