Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes
Abstract: Nickel‐catalyzed ipso‐borylations and silylations of aldehydes are described for the first time. The new functional‐group interconversion protocol is characterized by its scalability, functional‐group tolerance and wide substrate scope, including examples of late‐stage functionalization of complex molecules. The key for the successful reaction outcome is the use of a ketone as a hydride acceptor that intercepts the nickel hydride to undergo a reductive pathway, thus allowing formation of the desired C−B and C−Si bonds.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes ; volume:26 ; number:2 ; year:2020 ; pages:423-427 ; extent:5
Chemistry - a European journal ; 26, Heft 2 (2020), 423-427 (gesamt 5)
- Urheber
- DOI
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10.1002/chem.201904842
- URN
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urn:nbn:de:101:1-2022060809150381943893
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:23 MESZ
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Beteiligte
- Srimontree, Watchara
- Guo, Lin
- Rueping, Magnus
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