A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study

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Abstract 2) originating from the oxidation of VOCs. The measurement of HOMs is made by a NO3 - 2 SO4). The instrument response to HOMs is typically estimated using H2 SO4, as HOMs are neither commercially available nor easily synthesized in the laboratory. The resulting calibration factor is then applied to quantify all species detected using this technique. In this study, we explore the sensitivity of the instrument to commercially available small organic compounds, primarily dicarboxylic acids, given the limitations associated with producing known amounts of HOMs for calibration. We compare these single-compound calibration factors to the one obtained for H2 SO4 under identical operational conditions. The study found that the sensitivity of the NO3 - 3 - chemical-ionization mass spectrometer (CIMS), for example, HOMs.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO₃⁻ ToFCIMS) sensitivity study ; volume:17 ; number:15 ; year:2024 ; pages:4709-4724 ; extent:16
Atmospheric measurement techniques ; 17, Heft 15 (2024), 4709-4724 (gesamt 16)

Creator: Alage, Stéphanie
Michoud, Vincent
Harb, Sergio
Picquet-Varrault, Bénédicte
Cirtog, Manuela
Kumar, Avinash
Rissanen, Matti
Cantrell, Christopher

DOI: 10.5194/amt-17-4709-2024

URN: urn:nbn:de:101:1-2408150419381.173039429239

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 14.08.2025, 10:59 AM CEST

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Associated

Alage, Stéphanie
Michoud, Vincent
Harb, Sergio
Picquet-Varrault, Bénédicte
Cirtog, Manuela
Kumar, Avinash
Rissanen, Matti
Cantrell, Christopher

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A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO<sub>3</sub><sup>−</sup> ToFCIMS) sensitivity study

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A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO<sub>3</sub><sup>−</sup> ToFCIMS) sensitivity study

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A Nitrate Ion Chemical Ionization Atmospheric Pressure interface Time-of-Flight Mass Spectrometer (NO<sub>3</sub><sup>−</sup> ToFCIMS): calibration and sensitivity study

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A Nitrate Ion Chemical Ionization Atmospheric Pressure interface Time-of-Flight Mass Spectrometer (NO<sub>3</sub><sup>−</sup> ToFCIMS): calibration and sensitivity study

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