Access to Photoreactive Core‐Shell Nanomaterials by Photoinitiated Polymerization‐Induced Self‐Assembly
Abstract: We report the straightforward synthesis of photoreactive nanoobjects exhibiting various colloidal morphologies by photoinitiated polymerization‐induced self‐assembly (PISA). Poly (oligoethylene glycol methyl ether methacrylate) copolymers with pendent UV‐activatable diaryl tetrazole moieties were employed as macromolecular chain‐transfer agents in water for the dispersion photopolymerization of 2‐hydroxypropyl methacrylate under visible light. This led to the in situ formation of amphiphilic block copolymers, driving the self‐assembly into core‐shell nanoparticles, nanofibers, and nano/microvesicles. The tetrazole group present in the shell of the nanoobjects permitted functionalization with various functional molecules and polymers via UV‐triggered nitrile imine‐mediated tetrazole–ene cycloaddition (NITEC), enabling the alteration of surface properties of the nanomaterials (fluorescence, charge, hydrophilicity).
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Access to Photoreactive Core‐Shell Nanomaterials by Photoinitiated Polymerization‐Induced Self‐Assembly ; volume:3 ; number:11 ; year:2019 ; pages:1084-1089 ; extent:6
ChemPhotoChem ; 3, Heft 11 (2019), 1084-1089 (gesamt 6)
- Creator
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Molle, Edgar
Le, Dao
Norizadeh Abbariki, Tannaz
Akdemir, Meryem S.
Takamiya, Masanari
Miceli, Enrico
Kassel, Olivier
Delaittre, Guillaume
- DOI
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10.1002/cptc.201900216
- URN
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urn:nbn:de:101:1-2022081108370384159045
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:34 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Molle, Edgar
- Le, Dao
- Norizadeh Abbariki, Tannaz
- Akdemir, Meryem S.
- Takamiya, Masanari
- Miceli, Enrico
- Kassel, Olivier
- Delaittre, Guillaume
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Design of nanostructures : self-assembly of nanomaterials
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Cargo shuttling by electrochemical switching of core-shell microgels obtained by a facile one-shot polymerization
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Self-assembly of nanostructures and nanomaterials
Shape-Tunable Core−Shell Microparticles
Molecules at work : selfassembly, nanomaterials, molecular machinery
Design of nanostructures : self-assembly of nanomaterials
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