Blue‐LED Synthesis of Pummerer's Ketones by Peroxidase‐Lignin‐Catalyzed Oxidative Coupling of Substituted Phenols
Abstract: Pummerer's ketones resembling the tricyclic scaffold of bioactive natural substances were synthesized by blue‐LED driven Horseradish Peroxidase oxidative coupling of substituted phenols in 2‐methyltetrahydrofuran by using meso‐tetraphenylporphyrin as photosensitizer and dioxygen as primary oxidant. The application of functionalized lignin nanoparticles as a renewable and efficient platform for the immobilization of the enzyme extended the effectiveness of the overall process to heterogeneous catalysis under buffer limiting conditions.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Blue‐LED Synthesis of Pummerer's Ketones by Peroxidase‐Lignin‐Catalyzed Oxidative Coupling of Substituted Phenols ; day:24 ; month:07 ; year:2023 ; extent:8
European journal of organic chemistry ; (24.07.2023) (gesamt 8)
- Creator
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Piccinino, Davide
Ceccotti Vlas, Natalia
Gabellone, Sofia
Capecchi, Eliana
Saladino, Raffaele
- DOI
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10.1002/ejoc.202300356
- URN
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urn:nbn:de:101:1-2023072515020674551233
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:51 AM CEST
Data provider
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Associated
- Piccinino, Davide
- Ceccotti Vlas, Natalia
- Gabellone, Sofia
- Capecchi, Eliana
- Saladino, Raffaele
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