Metal–Organic Frameworks Derived from Zn and p ‐Hydroxybenzoic Acid for Smoke Suppression and Flame Retardation in Vinyl Resin

Abstract: A metal–organic framework (MOF) formed between Zn and p‐hydroxybenzoic acid (PHBA) is synthesized using a solvothermal method. These Zn‐PHBA nanorods, which are inexpensive and suitable for mass production, are added as a flame‐retardant into vinyl resin (430 LV, a material used in marine composites). Data from cone calorimetric test demonstrates that adding the Zn‐PHBA nanorods to 430 LV significantly improves flame retardation and smoke suppression. At a high Zn‐PHBA content of 10.0 wt%, the limiting oxygen index of 430 LV increases from 19.5% to 28.5%, and the material reaches the V‐0 rating in vertical burning tests (UL‐94). Moreover, the tensile and impact strengths of 430 LV containing 10 wt% Zn‐PHBA as flame‐retardant do not deteriorate and are even slightly improved. This work demonstrates that this MOF synthesized by a simple and efficient method may be used to produce nanocomposites with excellent flame retardation and mechanical properties, while keeping the material cost sufficiently low for marine applications.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Metal–Organic Frameworks Derived from Zn and p ‐Hydroxybenzoic Acid for Smoke Suppression and Flame Retardation in Vinyl Resin ; day:03 ; month:10 ; year:2022 ; extent:14
Macromolecular materials and engineering ; (03.10.2022) (gesamt 14)

Creator
Wang, Guorong
Mei, Zhiyuan
Li, Yu
Chen, Guotao
Xin, Jie
Sun, Zhaoyi
Wang, Qingxin
Luo, Xu

DOI
10.1002/mame.202200461
URN
urn:nbn:de:101:1-2022100415075588916790
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:25 AM CEST

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.

Associated

  • Wang, Guorong
  • Mei, Zhiyuan
  • Li, Yu
  • Chen, Guotao
  • Xin, Jie
  • Sun, Zhaoyi
  • Wang, Qingxin
  • Luo, Xu

Other Objects (12)