Controlling Chemoselectivity of Catalytic Hydroboration with Light
Abstract: The ability to selectively react one functional group in the presence of another underpins efficient reaction sequences. Despite many designer catalytic systems being reported for hydroboration reactions, which allow introduction of a functional handle for cross‐coupling or act as mild method for reducing polar functionality, these platforms rarely deal with more complex systems where multiple potentially reactive sites exist. Here we demonstrate, for the first time, the ability to use light to distinguish between ketones and carboxylic acids in more complex molecules. By taking advantage of different activation modes, a single catalytic system can be used for hydroboration, with the chemoselectivity dictated only by the presence or absence of visible light.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Controlling Chemoselectivity of Catalytic Hydroboration with Light ; day:11 ; month:01 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (11.01.2022) (gesamt 1)
- Creator
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Bergamaschi, Enrico
Lunic, Danijela
McLean, Liam A.
Hohenadel, Melissa
Chen, Yi‐Kai
Teskey, Christopher J.
- DOI
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10.1002/anie.202114482
- URN
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urn:nbn:de:101:1-2022011114112672088678
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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2025-08-15T07:23:02+0200
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Bergamaschi, Enrico
- Lunic, Danijela
- McLean, Liam A.
- Hohenadel, Melissa
- Chen, Yi‐Kai
- Teskey, Christopher J.
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