Visible-light-driven intermolecular reductive ene-yne coupling via iridium/coblat dual catalysis for C(sp3)-C(sp2) bond formation

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Abstract: A new methodology to form C(sp3)−C(sp2) bonds by visible‐light‐driven intermolecular reductive ene–yne coupling has been successfully developed. The process relies on the ability of the Hantzsch ester to contribute in both SET and HAT processes through a unified cobalt and iridium catalytic system. This procedure avoids the use of stoichiometric amounts of reducing metallic reagents, which is translated into high functional‐group tolerance and atom economy

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Notes: Chemistry - a European journal. - 25, 69 (2019) , 15746-15750, ISSN: 1521-3765

Keyword: Alkine
Cobalt
Katalyse
Photoredox-Katalyse
Reduktive Kupplungsreaktion

Event: Veröffentlichung

(where): Freiburg

(who): Universität

(when): 2020

Creator: González, María J.
Breit, Bernhard

DOI: 10.1002/chem.201903708

URN: urn:nbn:de:bsz:25-freidok-1520009

Rights: Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 14.08.2025, 10:51 AM CEST

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Associated

González, María J.
Breit, Bernhard
Universität

Time of origin

2020

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Visible-light-driven intermolecular reductive ene-yne coupling via iridium/coblat dual catalysis for C(sp3)-C(sp2) bond formation

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Other Objects (12)

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