Nickel‐Catalyzed Arylative Cyclizations of Alkyne‐ and Allene‐Tethered Electrophiles using Arylboron Reagents
Abstract: The use of arylboron reagents in metal‐catalyzed domino addition–cyclization reactions is a well‐established strategy for the preparation of diverse, highly functionalized carbo‐ and heterocyclic products. Although rhodium‐ and palladium‐based catalysts have been commonly used for these reactions, more recent work has demonstrated nickel catalysis is also highly effective, in many cases offering unique reactivity and access to products that might otherwise not be readily available. This review gives an overview of nickel‐catalyzed arylative cyclizations of alkyne‐ and allene‐tethered electrophiles using arylboron reagents. The scope of the reactions is discussed in detail, and general mechanistic concepts underpinning the processes are described.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Nickel‐Catalyzed Arylative Cyclizations of Alkyne‐ and Allene‐Tethered Electrophiles using Arylboron Reagents ; day:27 ; month:01 ; year:2022 ; extent:1
Chemistry - a European journal ; (27.01.2022) (gesamt 1)
- Urheber
-
Gillbard, Simone M.
Lam, Hon Wai
- DOI
-
10.1002/chem.202104230
- URN
-
urn:nbn:de:101:1-2022012814123607636700
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:33 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Gillbard, Simone M.
- Lam, Hon Wai
Ähnliche Objekte (12)
Nickel-Catalyzed anti-Selective Alkyne Functionalization Reactions
Enantioselective Nickel‐Catalyzed anti ‐Arylmetallative Cyclizations onto Acyclic Ketones
Nickel-catalyzed acylzincation of allenes with organozincs and CO
Regiocontrol in the Nickel-Catalyzed Aldehyde-Alkyne Reductive Coupling
Spirocyclization of Alkyne-Tethered Aromatics with Silver Nitrate/Silica
Dynamic Kinetic Resolution Strategy for the Asymmetric Nickel-Catalyzed Capture of Transient Cyclic Allenes
Intramolecular Carboxyamidation of Alkyne‐Tethered O ‐Acylhydroxamates through Formation of Fe (III)‐Nitrenoids
Skeletal and Mechanistic Diversity in Ir‐Catalyzed Cycloisomerizations of Allene‐Tethered Pyrroles and Indoles
Skeletal and Mechanistic Diversity in Ir‐Catalyzed Cycloisomerizations of Allene‐Tethered Pyrroles and Indoles
Cycloisomerization of Alkyne‐Tethered N ‐Acyloxycarbamates to 2‐(3H) Oxazolones through Nitrenoid‐Mediated Carboxyamidation
Catalytic 1,3‐H Atom Shift of a Terminal Benzylic Alkyne by Iron and Alkali Metal Silylamides – Switching between Allene and Internal Alkyne
DFT Mechanistic Insights into the Ni (II)‐Catalyzed Enantioselective Arylative Cyclization of Tethered Allene‐Ketones
Nickel-Catalyzed anti-Selective Alkyne Functionalization Reactions
Enantioselective Nickel‐Catalyzed anti ‐Arylmetallative Cyclizations onto Acyclic Ketones
Nickel-catalyzed acylzincation of allenes with organozincs and CO
Regiocontrol in the Nickel-Catalyzed Aldehyde-Alkyne Reductive Coupling
Spirocyclization of Alkyne-Tethered Aromatics with Silver Nitrate/Silica
Dynamic Kinetic Resolution Strategy for the Asymmetric Nickel-Catalyzed Capture of Transient Cyclic Allenes
Intramolecular Carboxyamidation of Alkyne‐Tethered O ‐Acylhydroxamates through Formation of Fe (III)‐Nitrenoids
Skeletal and Mechanistic Diversity in Ir‐Catalyzed Cycloisomerizations of Allene‐Tethered Pyrroles and Indoles
Skeletal and Mechanistic Diversity in Ir‐Catalyzed Cycloisomerizations of Allene‐Tethered Pyrroles and Indoles
Cycloisomerization of Alkyne‐Tethered N ‐Acyloxycarbamates to 2‐(3H) Oxazolones through Nitrenoid‐Mediated Carboxyamidation
Catalytic 1,3‐H Atom Shift of a Terminal Benzylic Alkyne by Iron and Alkali Metal Silylamides – Switching between Allene and Internal Alkyne
DFT Mechanistic Insights into the Ni (II)‐Catalyzed Enantioselective Arylative Cyclization of Tethered Allene‐Ketones
Nickel-Catalyzed anti-Selective Alkyne Functionalization Reactions
Enantioselective Nickel‐Catalyzed anti ‐Arylmetallative Cyclizations onto Acyclic Ketones
Nickel-catalyzed acylzincation of allenes with organozincs and CO
Regiocontrol in the Nickel-Catalyzed Aldehyde-Alkyne Reductive Coupling
Spirocyclization of Alkyne-Tethered Aromatics with Silver Nitrate/Silica
Dynamic Kinetic Resolution Strategy for the Asymmetric Nickel-Catalyzed Capture of Transient Cyclic Allenes
Intramolecular Carboxyamidation of Alkyne‐Tethered O ‐Acylhydroxamates through Formation of Fe (III)‐Nitrenoids
Skeletal and Mechanistic Diversity in Ir‐Catalyzed Cycloisomerizations of Allene‐Tethered Pyrroles and Indoles
Skeletal and Mechanistic Diversity in Ir‐Catalyzed Cycloisomerizations of Allene‐Tethered Pyrroles and Indoles
Cycloisomerization of Alkyne‐Tethered N ‐Acyloxycarbamates to 2‐(3H) Oxazolones through Nitrenoid‐Mediated Carboxyamidation
Catalytic 1,3‐H Atom Shift of a Terminal Benzylic Alkyne by Iron and Alkali Metal Silylamides – Switching between Allene and Internal Alkyne