Catalytic Reversible (De) hydrogenation To Rotate a Chemically Fueled Molecular Switch
Abstract: We report here the development of a rotating molecular switch based on metal‐catalyzed reversible (de)‐hydrogenation. Under an argon atmosphere, acceptorless dehydrogenation induces a switch from an alcohol to a ketone, while reversing to a hydrogen pressure switches back the system to the alcohol. Based on a tolane scaffold, such reversible (de)‐hydrogenation enables 180° rotation. The absence of waste accumulation in a switch relying on chemical stimuli is of great significance and could potentially be applied to the design of efficient complex molecular machines.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Catalytic Reversible (De) hydrogenation To Rotate a Chemically Fueled Molecular Switch ; day:15 ; month:11 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (15.11.2022) (gesamt 1)
- Urheber
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Olivieri, Enzo
Shao, Na
Rosas, Roselyne
Naubron, Jean‐Valère
Quintard, Adrien
- DOI
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10.1002/anie.202214763
- URN
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urn:nbn:de:101:1-2022111614025274038972
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:22 MESZ
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Beteiligte
- Olivieri, Enzo
- Shao, Na
- Rosas, Roselyne
- Naubron, Jean‐Valère
- Quintard, Adrien
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