Room Temperature Synthesis Mediated Porphyrinic NanoMOF Enables Benchmark Electrochemical Biosensing
Abstract: Leveraging size effects, nanoparticles of metal‐organic frameworks, nanoMOFs, have recently gained traction, amplifying their scopes in electrochemical sensing. However, their synthesis, especially under eco‐friendly ambient conditions remains an unmet challenge. Herein, an ambient and fast secondary building unit (SBU)‐assisted synthesis (SAS) route to afford a prototypal porphyrinic MOF, Fe‐MOF‐525 is introduced. Albeit the benign room temperature conditions, Fe‐MOF‐525 (SAS) nanocrystallites obtained are of ≈30 nm size, relatively smaller than the ones conventional solvothermal methods elicit. Integrating Fe‐MOF‐525 (SAS) as a thin film on a conductive indium tin oxide (ITO) surface affords Fe‐MOF‐525 (SAS)/ITO, an electrochemical biosensor. Synergistic confluence of modular MOF composition, analyte‐specific redox metalloporphyrin sites, and crystal downsizing contribute to its benchmark voltammetric uric acid (UA) sensing. Showcasing a wide linear range of UA detection with high sensitivity and low detection limit, this SAS strategy coalesces ambient condition synthesis and nanoparticle size control, paving a green way to advanced sensors.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Room Temperature Synthesis Mediated Porphyrinic NanoMOF Enables Benchmark Electrochemical Biosensing ; day:04 ; month:05 ; year:2023 ; extent:9
Small ; (04.05.2023) (gesamt 9)
- Creator
-
Zhou, Zhenyu
Wang, Jun
Hou, Shujin
Mukherjee, Soumya
Fischer, Roland A.
- DOI
-
10.1002/smll.202301933
- URN
-
urn:nbn:de:101:1-2023050415235639601467
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
14.08.2025, 10:50 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Zhou, Zhenyu
- Wang, Jun
- Hou, Shujin
- Mukherjee, Soumya
- Fischer, Roland A.
Other Objects (12)
High‐Quality Thin Films of UiO‐66‐NH 2 by Coordination Modulated Layer‐by‐Layer Liquid Phase Epitaxy
Porphyrinischer MOF‐Film für vielfältige elektrochemische Sensorik
Porphyrinic MOF Film for Multifaceted Electrochemical Sensing
Exploitation of Intrinsic Confinement Effects of MOFs in Catalysis
Tuning the Properties of MOF‐808 via Defect Engineering and Metal Nanoparticle Encapsulation
Avoiding Pyrolysis and Calcination: Advances in the Benign Routes Leading to MOF‐Derived Electrocatalysts
Elucidating Dynamic Responsiveness in Model Rigid and Flexible Metal-Organic Frameworks
Copper-Paddlewheel-Based Surface Mounted Metal-Organic Framework Thin Films
Encapsulation of mono- and bimetallic nanoparticles into metal-organic frameworks
Linker functionalization as a tool for imparting functionality into metal-organic frameworks
Untersuchungen über Modellexperimente des Chemieunterrichts, dargestellt am Beispiel der Mehlstaubexplosion
Engineering functional metal-organic framework thin film devices
High‐Quality Thin Films of UiO‐66‐NH 2 by Coordination Modulated Layer‐by‐Layer Liquid Phase Epitaxy
Porphyrinischer MOF‐Film für vielfältige elektrochemische Sensorik
Porphyrinic MOF Film for Multifaceted Electrochemical Sensing
Exploitation of Intrinsic Confinement Effects of MOFs in Catalysis
Tuning the Properties of MOF‐808 via Defect Engineering and Metal Nanoparticle Encapsulation
Avoiding Pyrolysis and Calcination: Advances in the Benign Routes Leading to MOF‐Derived Electrocatalysts
Elucidating Dynamic Responsiveness in Model Rigid and Flexible Metal-Organic Frameworks
Copper-Paddlewheel-Based Surface Mounted Metal-Organic Framework Thin Films
Encapsulation of mono- and bimetallic nanoparticles into metal-organic frameworks
Linker functionalization as a tool for imparting functionality into metal-organic frameworks
Untersuchungen über Modellexperimente des Chemieunterrichts, dargestellt am Beispiel der Mehlstaubexplosion
Engineering functional metal-organic framework thin film devices
High‐Quality Thin Films of UiO‐66‐NH 2 by Coordination Modulated Layer‐by‐Layer Liquid Phase Epitaxy
Porphyrinischer MOF‐Film für vielfältige elektrochemische Sensorik
Porphyrinic MOF Film for Multifaceted Electrochemical Sensing
Exploitation of Intrinsic Confinement Effects of MOFs in Catalysis
Tuning the Properties of MOF‐808 via Defect Engineering and Metal Nanoparticle Encapsulation
Avoiding Pyrolysis and Calcination: Advances in the Benign Routes Leading to MOF‐Derived Electrocatalysts
Elucidating Dynamic Responsiveness in Model Rigid and Flexible Metal-Organic Frameworks
Copper-Paddlewheel-Based Surface Mounted Metal-Organic Framework Thin Films
Encapsulation of mono- and bimetallic nanoparticles into metal-organic frameworks
Linker functionalization as a tool for imparting functionality into metal-organic frameworks
Untersuchungen über Modellexperimente des Chemieunterrichts, dargestellt am Beispiel der Mehlstaubexplosion