Organometallic Borromean Rings and (2) Catenanes Featuring Di‐ NHC Ligands
Abstract: We report herein a series of organometallic Borromean rings (BRs) and [2]catenanes prepared from benzobiscarbene ligands. The reaction of dinickel complexes of the benzobiscarbenes 1 a–1 c with a thiazolothiazole bridged bipyridyl ligand L2 led by self‐assembly to a series of organometallic BRs. Solvophobic effects played a crucial role in the formation and stability of the interlocked species. The stability of BRs is related to the N‐alkyl substituents at the precursors 1 a–1 c, where longer alkyl substitutes improve stability and inter‐ring interactions. Solvophobic effects are also important for the stability of [2]catenanes prepared from 1 a–1 c and a flexible bipyridyl ligand L3. In solution, an equilibrium between the [2]catenanes and their macrocyclic building blocks was observed. High proportions of [2]catenanes were obtained in concentrated solutions or polar solvents. The proportion of [2]catenanes in solution could be further enhanced by lengthening of the N‐alkyl substitutes.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Organometallic Borromean Rings and (2) Catenanes Featuring Di‐ NHC Ligands ; day:03 ; month:02 ; year:2023 ; extent:8
Angewandte Chemie / International edition. International edition ; (03.02.2023) (gesamt 8)
- Urheber
- DOI
-
10.1002/anie.202217681
- URN
-
urn:nbn:de:101:1-2023020414120838043594
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 14.08.2025, 10:51 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Lu, Ye
- Dutschke, Patrick D.
- Kinas, Jenny
- Hepp, Alexander
- Jin, Guo-Xin
- Hahn, Franz Ekkehardt
Ähnliche Objekte (12)
Organometallic Borromean Rings and (2) Catenanes Featuring Di‐ NHC Ligands
Design, synthesis and postsynthetic modifications of metallosupramolecular architectures featuring poly-NHC ligands
Actinide Organometallic Complexes with π‐Ligands
Organometallic chemistry of multidentate imidazolin-2-imine ligands
Key intermediates in NHC-catalyzed reactions of activated esters and novel NHC ligands for gold catalysis
Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
Rhodium(III) and iridium(III) complexes bearing chelating C(pNHC)^phosphine or C(pNHC)^C(NHC) ligands: synthesis and catalytic applications
Dinuclear Au(I) Complexes Bearing Bridge-Functionalized NHC Ligands as Anticancer Agents
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers
Nickel (II) and Iron (II) Complexes with Tetradentate NHC/Amide Hybrid Ligands
Ring Contraction by NHC‐Induced Pnictogen Abstraction
Towards New Organometallic Wires: Tetraruthenium Complexes Bridged by Phenylenevinylene and Vinylpyridine Ligands
Organometallic Borromean Rings and (2) Catenanes Featuring Di‐ NHC Ligands
Design, synthesis and postsynthetic modifications of metallosupramolecular architectures featuring poly-NHC ligands
Actinide Organometallic Complexes with π‐Ligands
Organometallic chemistry of multidentate imidazolin-2-imine ligands
Key intermediates in NHC-catalyzed reactions of activated esters and novel NHC ligands for gold catalysis
Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
Rhodium(III) and iridium(III) complexes bearing chelating C(pNHC)^phosphine or C(pNHC)^C(NHC) ligands: synthesis and catalytic applications
Dinuclear Au(I) Complexes Bearing Bridge-Functionalized NHC Ligands as Anticancer Agents
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers
Nickel (II) and Iron (II) Complexes with Tetradentate NHC/Amide Hybrid Ligands
Ring Contraction by NHC‐Induced Pnictogen Abstraction
Towards New Organometallic Wires: Tetraruthenium Complexes Bridged by Phenylenevinylene and Vinylpyridine Ligands
Organometallic Borromean Rings and (2) Catenanes Featuring Di‐ NHC Ligands
Design, synthesis and postsynthetic modifications of metallosupramolecular architectures featuring poly-NHC ligands
Actinide Organometallic Complexes with π‐Ligands
Organometallic chemistry of multidentate imidazolin-2-imine ligands
Key intermediates in NHC-catalyzed reactions of activated esters and novel NHC ligands for gold catalysis
Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
Rhodium(III) and iridium(III) complexes bearing chelating C(pNHC)^phosphine or C(pNHC)^C(NHC) ligands: synthesis and catalytic applications
Dinuclear Au(I) Complexes Bearing Bridge-Functionalized NHC Ligands as Anticancer Agents
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers
Nickel (II) and Iron (II) Complexes with Tetradentate NHC/Amide Hybrid Ligands
Ring Contraction by NHC‐Induced Pnictogen Abstraction